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Macrocycles have been widely studied for their structure-specific and highly selective recognition properties. Here the authors review the design, synthesis and applications of photo-, pH- and redox-responsive macrocycles.
Photochemical and electrochemical approaches to protein and peptide modification offer a valuable complement to the use of stoichiometric reagents. Here recent developments in bioconjugation methodology relying on single electron transfer are described.
Aluminum dual-ion batteries have attracted considerable attention due to their low cost, safety, high energy density, energy efficiency, and long cycling life. Here the authors review working principles, electrolytes, and corrosion effects of this battery type.
Bis(arylimino)acenaphthene ligands were recognized as robust scaffolds for metal complexes decades ago, but their redox non-innocence as well as their potential to mediate electro- or photo-catalysis remain subjects of active research. Here, the authors review the synthesis and properties of these poly-aromatic diimine ligands complexed to nominally redox-innocent p-block elements.
While the bulk structures of metal–organic frameworks can be solved by diffraction-based techniques, characterization of their local structures has been lacking. Here the authors review recent advances in (scanning) transmission electron microscopy that have made it possible to probe the local structures of MOFs at atomic resolution.
In celebration of International Women’s Day, on 6 March 2020 the University of Nottingham hosted its second Women in Chemistry conference. Or, as branded by a security guard at the host building, a ‘chemical ladies’ meeting’. Victoria Richards recounts the event and shares key take-home messages from the speakers.
Colour polymorphism is a rare phenomenon that occurs when a compound possesses packing or conformational polymorphs of different colours. Here the authors review representative chemical systems that display colour polymorphism and explore the origins of this property.
Graphene-based materials are widely studied in biomedical applications, but a full picture of their interactions with proteins and cells remains elusive. Here the molecular basis for the effect of graphene-based materials on cell fate and in tissue engineering is reviewed.