Featured
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Kinetics of electrochemical dissolution of metals in porous media
A model is proposed to predict the corrosion rate of steels embedded in different porous media including concrete, wood and soil. It relies on the moisture state and the pore structure, which affect the electrochemical dissolution kinetics.
- Matteo Stefanoni
- , Ueli M. Angst
- & Bernhard Elsener
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Predictive model of hydrogen trapping and bubbling in nanovoids in bcc metals
A model is established to quantitatively predict hydrogen energetics and molecule formation in nanovoids of bcc metals, clarifying the trapping and bubbling mechanisms for understanding hydrogen-induced damage.
- Jie Hou
- , Xiang-Shan Kong
- & C. S. Liu
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Article |
Decoupling the role of stress and corrosion in the intergranular cracking of noble-metal alloys
The model alloy of Au–Ag is studied to decouple the role of stress and corrosion in intergranular cracking caused by metal dissolution. Nanoporous corrosion layers can mechanically inject a crack into grain boundaries of the parent phase.
- N. Badwe
- , X. Chen
- & K. Sieradzki
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News & Views |
Still plenty to explore
Advanced characterization and modelling techniques provide unique insights into oxidant transport processes in growing scales of high-temperature alloys and alloy design for improving their degradation resistance in harsh environments.
- Brian Gleeson
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Article |
Interplay of water and reactive elements in oxidation of alumina-forming alloys
The crucial interaction between reactive elements and water vapour during the oxide scale growth of alumina-forming alloys is revealed, providing insights to improve corrosion resistance of high-temperature alloys.
- N. Mortazavi
- , C. Geers
- & L. G. Johansson
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Article |
A high-specific-strength and corrosion-resistant magnesium alloy
A magnesium-based alloy with large lithium content demonstrates high specific strength in combination with corrosion resistance, associated with the formation of a lithium carbonate surface film that protects the alloy from its environment.
- Wanqiang Xu
- , Nick Birbilis
- & Michael Ferry
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News & Views |
Sharpened interface
The finding of a sharp interface between a chemically attacked surface and the pristine bulk in a borosilicate glass is at odds with the widely held diffusion-based mechanisms of glass durability.
- Andrew Putnis
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Letter |
Spontaneous evolution of bicontinuous nanostructures in dealloyed Li-based systems
For alloys displaying diffusive transport behaviour, understanding the electrochemical factors that control dealloying-induced morphologies could prove important for battery development. Composition, particle size and dealloying rate are now shown to affect morphology evolution in the Li–Sn system, and dealloying is found to be governed by both percolation-dissolution and solid-state-diffusion mechanisms.
- Qing Chen
- & Karl Sieradzki