Research articles

Oxides with a face-centred cubic anion sublattice are generally not considered as solid-state electrolytes. Li superionic conductivity in face-centred cubic oxides with face-sharing Li configurations have now been created through cation over-stoichiometry in rocksalt-type lattices via excess Li.

Intense light pulses can induce symmetry breaking, as for the generation of ferroelectricity in SrTiO₃. Using ultrafast X-ray diffuse scattering at a free-electron laser, nonlinear phonon interactions that occur on such mid-IR excitation are observed, with a theory for the dynamics presented.

Soft building blocks tend to be near spherical, limiting their packing structures to those found in metallic systems. Here the authors report the spontaneous generation of highly deformed mesoatoms using molecular pentagons and observe Frank–Kasper phases not found in metal alloys.

A general process for a room-temperature, homogeneous Suzuki–Miyaura-type polymerization is reported, demonstrating a route for the scalable production of device-quality conjugated polymers.

Although silicon anodes are promising for solid-state batteries, they still suffer from poor electrochemical performance. Chemo-mechanical failure mechanisms of composite Si|Li₆PS₅Cl and solid-electrolyte-free silicon anodes are now revealed and should help in designing improved electrodes.

Samples of NdNiO_2+x are prepared with meticulous control of the oxygen content. Their X-ray scattering and spectroscopy measurements then reveal that the previously reported charge density wave in undoped infinite-layer nickelates is, in fact, a spurious effect.

The authors demonstrate field-free magnetization switching in van der Waals heterostructures.

The authors study spin transport anisotropy in a 5.5 nm black phosphorus ribbon encapsulated by boron nitride.

NiFe-based oxo-hydroxides are active for the oxygen evolution reaction but suffer from complex synthesis and durability when deposited. Easily processable Fe–Ni alloys with a highly active oxo-hydroxide surface are now shown to pave the way for oxygen-evolving electrodes for alkaline water electrolysers.

Direct observation of noble gas structures has been achieved at room temperature using electron microscopy. This was enabled by trapping them between two layers of graphene, where they form two-dimensional clusters.

Quantifying recombination in halide perovskites is crucial, but quantitative analysis remains rare. Here the authors observe a long-lived and continuously changing photoluminescence decay time due to the high density of shallow defects and substantial rates of charge carrier trapping.

Hydrogen produced by water splitting using renewable electricity is key to achieve net-zero carbon emissions. Decoupling hydrogen and oxygen evolution reactions during electrolysis is attractive but efficiency and operational challenges remain. A process producing hydrogen and oxygen in separate cells and supporting continuous operation in a membraneless system is now proposed.

The authors propose a non-Hermitian topological insulator with a real-valued energy spectrum based on a periodically driven Floquet model implemented in a photonic platform where generalized parity–time symmetry is protected against spontaneous symmetry breaking under a spatiotemporal gain and loss distribution.

Propagation losses have limited the practical use of polaritons in photonic applications. Here the authors demonstrate a substantial enhancement in the propagation distance of phonon polaritons, employing synthetic optical excitation of complex frequency with virtual gain synthesized by combining multiple real frequency measurements.

The local layer alignment in a wide range of trilayer graphene structures has been extracted by interferometric four-dimensional scanning transmission electron microscopy, uncovering the complex picture of lattice reconstruction in twisted trilayers.

The metal monochalcogenides are a group of van der Waals layered semiconductors with ultra-high plasticity. It is now revealed that their plasticity is attributed to the ability to transform their stacking order or phases, coupled with the concurrent generation of a micro-crack network.

Interfacial reactions between lithium and anodes are not well understood in an all-solid environment. For the silicon anode we now demonstrate that, rather than strong Li–Si alloying at the conventional solid–liquid interface, the lithiation reaction of micrometre-sized Si can be greatly constricted at the solid–solid interface.

Employing light-transformable polymers, multiple physical unclonable functions are demonstrated within a single device with all-optical reversible reconfigurability. Such devices may enable quantum secure authentication and nonlinear cryptographic key generation applications.

Current organic proton detectors have poor detection sensitivities due to low light yields and limited radiation toleration. Here the authors report a perovskite nanocrystal-based transmissive thin scintillator that can detect seven protons per second, enabled by radiative emission from biexcitons.

Biological tissues are extremely water rich but remain mechanically stiff, behaviour that is difficult to recapitulate in synthetic materials. Here the authors design a hydrogel/sponge hybrid material driven by a self-organized network of cyano-p-aramid nanofibres that combines these properties for biofunctional materials.