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This special issue gives a comprehensive discussion of CDs around the following key points: Synthesis for targeted structures and properties; photoluminescence phenomena and mechanisms; and emerging applications and future directions. The amount of related papers are yearly progressive increase indicates that CDs as promising nanomaterials are indeed getting a lot of attention. Thus, it is extremely important to promote the development of CDs. This special issue is also aimed to discuss about some critical issues and possible solutions to potentially address these issues.
Confined-domain crosslink-enhanced emission effect was first studied to reveal the photoluminescence mechanism of carbonized polymer dots (CPDs). A general strategy was exploited to synthesize CPDs exhibiting tunable photoluminescence properties.
This review focuses on chiral carbon dots, introducing their chemical syntheses, morphology and optical/chiroptical properties, and considering their emerging applications in sensing, bioimaging and catalysis.
Using different chiral precursor molecules, we produced chiral CDs with superior optical properties, such as two-photon absorption, high photoluminescence quantum yield reaching 57%, and chiral signals in the UV-Vis spectral region.
Ultraviolet high-energy photons of phosphorescent carbon dots for antibacterial applications. Herein, the UV phosphorescent CNDs were achieved by decreasing conjugation size and spatial confinement. As a demonstration, the CNDs are used to inactivate gram-negative/positive bacteria.
Core-shell structured Au@carbon dots are fabricated to present a photoinduced-enhanced oxidative stress amplification, which can be efficiently used for tumor catalytic therapy by surface-enhanced Raman scattering technique.
The fluorophore source of red emissive oPD&CAT system CDs is the 5,14-dihydroquinoxalino[2,3-b] phenazine (DHQP), formed in the initial reaction stage. Subsequently, the DHQP was connected with carbon core. The excited electrons of the molecular state can transfer into the energy level of CDs, which leads to UV excitation red emissive intensity decreased.