Although caesium is well known in its oxidation state +I, many chemists have speculated about a possible higher state. Such a species has not yet been prepared, but based on quantum-chemical calculations CsFn compounds have now been predicted to be stable.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 12 print issues and online access
$259.00 per year
only $21.58 per issue
Buy this article
- Purchase on SpringerLink
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
References
Wang, X., Andrews, L., Riedel, S. & Kaupp, M. Angew. Chem. Int. Ed. 46, 8371–8375 (2007).
Gong, Y., Zhou, M., Kaupp, M. & Riedel, S. Angew. Chem. Int. Ed. 48, 7879–7883 (2009).
Miao, M.-S. Nature Chem. 5, 846–852 10.1038/nchem.1754(2013).
Pyykkö, P. Chem. Rev. 88, 563–594 (1988).
Grochala, W., Hoffmann, R., Feng, J. & Ashcroft, N. W. Angew. Chem. Int. Ed. 46, 3620–3642 (2007).
McMahon, J. M., Morales, M. A., Pierleoni, C. &. Ceperley, D. M. Rev. Mod. Phys. 84, 1607–1653 (2012).
Guillaume, C. L. et al. Nature Phys. 7, 211–214 (2011).
Struzhkin, V. V. et al. Nature 390, 382–383 (1997).
Kurzydłowskia, D. & Grochala, W. Chem. Commun. 1073–1075 (2008).
Riedel, S., Köchner, T., Wang, X. & Andrews, L. Inorg. Chem. 49, 7156–7164 (2010).
Ault, B. S. & Andrews, L. J. Am. Chem. Soc. 98, 1591–1593 (1976).
Takemura, K., Minomura, S. & Shimomura, O. Phys. Rev. Lett. 49, 1772–1775 (1982).
Huber, K. P. & Herzberg, G. Molecular Spectra and Molecular Structure 4: Constants of Diatomic Molecules (Van Nostrand, 1979).
Shannon, R. D. Acta Cryst. A32, 751–767 (1976).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Riedel, S., Schwerdtfeger, P. Beyond state I. Nature Chem 5, 815–816 (2013). https://doi.org/10.1038/nchem.1767
Published:
Issue Date:
DOI: https://doi.org/10.1038/nchem.1767