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Isolation and Identification of Sterols from a Pleistocene Sediment

Abstract

BECAUSE of their chemical stability, alkanes and fatty acids have been widely used as indicators of biological origin in studies of sediments1–4, but their formation may often be attributable to abiogenic syntheses and transformations5 so that their distribution patterns should be approached with caution. Little effort has been expended on analysis of sediments for relatively unaltered molecules which are biologically more significant, such as sterols which are present in sea water6, bottom muds (both marine and non-marine)7,8, surface soils9, and an Eocene shale10. If such molecules are present in sediments representing a wide period of geological time, their significance with regard to depositional environment and contributory organisms would exceed any other biological marker in common use. We report some organic geochemical studies of a Pleistocene basin and a contemporary lake where we are attempting to correlate alkane, fatty acid, steroid, amino-acid and sugar distribution patterns with stratigraphy and biological environment.

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References

  1. Eglinton, G., in Advances in Organic Geochemistry (edit. by Schenck, P. A., and Havenaar, I.), 1 (Pergamon Press, Oxford, 1968).

    Google Scholar 

  2. Blumer, M., and Cooper, W. J., Science, 158, 1463 (1967).

    Article  ADS  CAS  Google Scholar 

  3. Oró, J., Nooner, D. W., Zlatkis, A., Wikström, S. A., and Barghoorn, E. S., Science, 148, 77 (1965).

    Article  ADS  Google Scholar 

  4. Henderson, W., Wollrab, V., and Eglinton, D., in Advances in Organic Geochemistry (edit. by Schenck, P. A., and Havenaar, I.), 181 (Pergamon Press, Oxford, 1968).

    Google Scholar 

  5. Studier, M. H., Hayatsu, R., and Anders, E., Geochim. Cosmochim. Acta, 32, 151 (1968).

    Article  ADS  CAS  Google Scholar 

  6. Matthews, W. S., and Smith, L. L., Lipids, 3, 239 (1968).

    Article  CAS  Google Scholar 

  7. Schwendinger, R. B., and Erdman, J. G., Science, 144, 1575 (1964).

    Article  ADS  CAS  Google Scholar 

  8. Attaway, D., and Parker, P. L., Science, 169, 674 (1970).

    Article  ADS  CAS  Google Scholar 

  9. Meinschein, W. G., and Kenny, G. S., Anal. Chem., 29, 1153 (1957).

    Article  CAS  Google Scholar 

  10. Mattern, G., Albrecht, P., and Ourisson, G., Chem. Commun., 1570 (1970).

  11. Gilbert, C. M., Christensen, M. N., Al-Rawi, Y., and Lajoie, K. R., in Studies in Volcanology (edit. by Coats, R. R., Hay, R. L., and Anderson, C. A.), Memoir 116 (Geological Society of America, 1968).

    Google Scholar 

  12. Lajoie, K. R., thesis, Univ. California, Berkeley (1968).

  13. McCarthy, R. D., and Duthie, A. H., J. Lipid Res., 3, 117 (1962).

    CAS  Google Scholar 

  14. Reitz, R. C., and Hamilton, J. G., Biochem. Physiol., 25, 401 (1968).

    CAS  Google Scholar 

  15. de Souza, N. J., and Nes, W. R., Science, 162, 363 (1968).

    Article  ADS  CAS  Google Scholar 

  16. Ikekawa, N., Morisaki, N., Tsuda, K., and Yoshida, T., Steroids, 12, 41 (1968).

    Article  CAS  Google Scholar 

Download references

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HENDERSON, W., REED, W., STEEL, G. et al. Isolation and Identification of Sterols from a Pleistocene Sediment. Nature 231, 308–310 (1971). https://doi.org/10.1038/231308a0

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