Abstract
THE magnetic properties of several iron (III) compounds with antiferromagnetic properties have recently been accounted for within the framework of the dipolar coupling model1,2. One such compound—(Fe salen)2O.py2 (salen = bis-salicylidene–ethylenediamine)1, has a moment of ∼ 1.90 B.M. at 300° K, falling to ∼ 0.58 B.M. at 80° K—has been fitted with an exchange integral of 90 cm−1. The crystal structure of this complex is reported here.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Lewis, J., Mabbs, F. E., and Richards, A., J. Chem. Soc. A, 1014 (1967).
Gerloch, M., Lewis, J., Mabbs, F. E., and Richards, A., J. Chem. Soc. A., 112 (1968).
Lippard, S. J., Schugar, H., and Walling, C., Inorg. Chem., 6, 1825 (1967).
Gerloch, M., and Mabbs, F. E., J. Chem. Soc. A, 1598 (1967).
Gerloch, M., and Mabbs, F. E., J. Chem. Soc. A, 1900 (1967).
Vogt, jun., L. H., Zalkin, A., and Templeton, D. H., Inorg. Chem., 6, 1725 (1967).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
GERLOCH, M., MCKENZIE, E. & TOWL, A. An Oxo-bridged Five-coordinate Iron(III) Molecule. Nature 220, 906–907 (1968). https://doi.org/10.1038/220906a0
Received:
Issue Date:
DOI: https://doi.org/10.1038/220906a0
This article is cited by
-
X-ray crystal structure determination of (Fesalen)2O � CH2Cl2
Journal of Structural Chemistry (1970)
-
Infrared Evidence for an Oxo-bridged (Fe-O-Fe) Haemin Dimer
Nature (1969)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.
