Abstract
THE radiolysis of dilute solutions of aromatic hydrocarbons results in the production of high yields of electronically excited solute molecules1–3. The results of charge-scavenging experiments2,3 indicate that the most probable process for the production of electronically excited solute molecules in cyclohexane solutions is charge transfer to the solute followed by charge neutralization. One would expect the application of an electric field to influence the yield of products obtained from these charge neutralization processes. We have investigated the influence of electric field on the yield of electronically excited singlet state solute molecules by investigating the radiation induced fluorescence from cyclohexane solutions of anthracene (A) and pyrene (P) in the presence of an electric field.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
McCollum, J. D., and Nevitt, T. D., US Tech. Rep., ASD-TDR-63-616 (1963).
Kemp, T. J., Roberts, J. P., Salmon, G. A., and Thompson, G. F., Proc. Second Tihany Symp. Radiat. Chem., 333 (Akademiai Kiado, Budapest, 1967).
Dainton, F. S., Salmon, G. A., Morrow, T., and Thompson, G. F., Chem. Comm., 326 (1968).
Talrose, V. L., Actions Chimiques et Biologiques des Radiations (edit. by Haissinsky, M.), 11, Ch. 2 (Academic Press and Masson et Cie, Paris, 1967).
Freeman, G. R., J. Chem. Phys., 39, 1580 (1963).
Freeman, G. R., and Fayadh, J. M., J. Chem. Phys., 43, 86 (1965).
Chandross, E. A., Longworth, J. W., and Visco, R. E., J. Amer. Chem. Soc., 87, 3257 (1965).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
MORROW, T., SALMON, G. & FRANKEVICH, E. Effect of an Electric Field on the Radiation Induced Fluorescence from Solutions of Aromatic Hydrocarbons in Cyclohexane. Nature 219, 481–482 (1968). https://doi.org/10.1038/219481a0
Received:
Issue Date:
DOI: https://doi.org/10.1038/219481a0
This article is cited by
-
Fluorescence of squid axon membrane labelled with hydrophobic probes
The Journal of Membrane Biology (1972)
-
Changes in extrinsic fluorescence intensity of the electroplax membrane during electrical excitation
The Journal of Membrane Biology (1971)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.