Abstract
VALUES of ΔGass (Table 1) have been measured for the reactions 
where L− is OH− or F− and ML2+ are the hydroxyl complexes of the cations Ti3+ to Co3+ or the fluoride complexes of Fe3+ and Cr3+. Here a correlation is demonstrated between a function involving ΔGass and ΔGredox for the overall electron-transfer process 
which indicates a charge-transfer structure for the associated species, M3+L−↔M2+L.
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ROSSEINSKY, D. Charge Transfer in Mono-hydroxo and Mono-fluoro Complexes of Tripositive Cations in the First Transition Series. Nature 216, 791–793 (1967). https://doi.org/10.1038/216791a0
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DOI: https://doi.org/10.1038/216791a0
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