Mechanism for Anomalous OH Emission from H^II Regions

Abstract

SEVERAL suggestions have been made to explain the formation of OH in the galaxy, together with possible pumping mechanisms to produce the laser action considered responsible for high anomalous brightness temperatures at least as high as 10¹⁰ °K (ref. 1). It is usually assumed that OH is produced in the presence of interstellar particles by sputtering or by a process of chemical exchange on the particles; they also act as the third body and help to conserve energy and momentum. The pumping mechanism suggested by Litvak et al.² is by continuum ultra-violet radiation which induces selective transitions from the various rotational levels of the (X²II) ground state to the (A²Σ) electronic excited state. By this means an inversion of the population of the ground doublet state is obtained, but on the other hand the energies involved are close to the dissociation energy for OH. The analysis by Cook³ invokes pumping by Lyman-α radiation, but again the energy involved is more than twice the dissociation energy and it is likely that a large percentage of the OH would be dissociated. The two-body process proposed by Symonds⁴ of forming excited OH from O− and H+ could possibly also provide the pumping mechanism, but unfortunately it requires the liberation of a large amount of energy and it seems unlikely that this process would be effective. A more interesting mechanism has recently come to light with the observation in the laboratory by Spindler et al.⁵ of the formation of OH in an electronically excited state, as a two-body process involving atomic oxygen and hydrogen, with the emission of radiation in the 3064 Å band. The rate for the reaction has been determined⁶, and can be expressed by where I, the intensity of the emission, is assumed equal to the rate of formation of OH molecules, [H] and [O] are the densities of atomic hydrogen and oxygen respectively, and K = 3 × 10⁻²¹ molecules cm⁻³ sec⁻¹ is the rate constant at room temperature. Because this reaction could well be taking place in the cooler parts surrounding individual H^II regions it is of interest to assess the possibility that it is also the cause of anomalous OH emission.