Abstract
IN chemical kinetics the effect of temperature on reaction rates is often evaluated in terms of the activation parameters E and A of the Arrhenius equation1,2 where k is an appropriate rate coefficient at the absolute temperature T, A is a constant related to the entropy of activation, E is the activation energy and R is the gas constant. In practice the numerical value of E is derived from the slope m of the graph log k versus l/T, and E = 2.303 Rm when common logarithms are used; log A is usually obtained by substituting the corresponding values of k, E and T in the logarithmic form of the equation.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Hinshelwood, C. N., The Kinetics of Chemical Change (Oxford University Press, Oxford, 1940).
Frost, A. A., and Pearson, R. G., Kinetics and Mechanism (John Wiley, New York, 1953).
Glasstone, S., Laidler, K. J., and Eyring, H., The Theory of Rate Processes (McGraw-Hill, New York, 1941).
Johnson, F. H., Eyring, H., and Polissar, M. J., The Kinetic Basis of Molecular Biology (John Wiley, New York, 1954).
Good, W., Biochim. Biophys. Acta, 44, 130 (1960).
Leffler, J. E., J. Org. Chem., 20, 1202 (1955).
Brown, R. F., J. Org. Chem., 27, 3015 (1962).
Blackadder, D. A., and Hinshelwood, C. N., J. Chem. Soc., 2720 (1958).
Petersen, R. C., Markgraf, J. H., and Ross, S. D., J. Amer. Chem. Soc., 83, 3819 (1961).
Exner, O., Nature, 201, 488 (1964).
McGregor, R., and Millecevic, B., Nature 21l, 523 (1966).
Trincher, K. S., Biofizika, 9, 633 (1964).
Hechter, O., Fed. Proc., 24, S 91 (1965).
Ives, D. J. G., and Marsden, P. D., J. Chem. Soc., 649 (1965).
Good, W., Biochim. Biophys. Acta, 57, 104 (1962).
Good, W., Biochim. Biophys. Acta, 52, 545 (1961).
Good, W., Biochim. Biophys. Acta, 53, 549 (1961).
Good, W., Electrochim. Acta, 9, 203 (1964).
Good, W., Biochim. Biophys. Acta, 50, 485 (1961).
Hendry, E. B., J. Gen. Physiol., 35, 605 (1952).
Good, W., Biochim. Biophys. Acta, 56, 359 (1962).
Jones, G., and Talley, S. K., J. Amer. Chem. Soc., 55, 624 (1933).
Shimura, K., J. Agr. Chem. Soc. Japan, 24, 412 (1950).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
GOOD, W. A Biological Example of the Compensation Law. Nature 214, 1250–1252 (1967). https://doi.org/10.1038/2141250a0
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1038/2141250a0
This article is cited by
-
The permeability of liposomes to nonelectrolytes
The Journal of Membrane Biology (1975)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.