Abstract
INFORMATION about the structure of the ion formed when p-nitroso-N, N -dimethylaniline (I) accepts a proton can be derived from the high resolution proton magnetic resonance spectrum, and it is possible to discriminate between the oxygen protonated form (II) and the nitrogen protonated form (III).
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Davies, W. C., and Addis, H. W., J. Chem. Soc., 1622 (1937).
Randles, J. E. B., and Tedder, J. M., J. Chem. Soc., 1218 (1955).
Nakamoto, K., and Rundle, R. E., J. Amer. Chem. Soc., 78, 1113 (1956).
Wallace, R., thesis, Univ. Glasgow (1964).
Pople, J. A., Schneider, W. G., and Bernstein, H. J., High-resolution Nuclear Magnetic Resonance. chapt. 10 (McGraw-Hill, New York, 1959).
MacNicol, D. D., Wallace, R., and Brand, J. C. D., Trans. Farad. Soc., 61, 1 (1965).
Glasstone, S., Laidler, K. J., and Eyring, M., The Theory of Rate Processes, 194 (McGraw-Hill, New York, 1941).
Ingold, C. K., Structure and Mechanism in Organic Chemistry, chapt. 2 (Bell and Sons, Ltd., London, 1953).
Taylor, T. W. J., and Baker, W., Sidgwick's Organic Chemistry of Nitrogen, 219 (Clarendon Press, Oxford, 1937).
See Bothner-By, A. A., in Adv. Magnetic Resonance (edit. by Waugh, J. S.), 1, 195 (Academic Press, London, 1965).
Jones, G. T., and Murrell, J. N., J. Chem. Soc., A, 1421 (1966).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
MACNICOL, D., PORTE, A. & WALLACE, R. Structure of the Conjugate Acid of p-Nitroso-N, N-dimethylaniline. Nature 212, 1572–1573 (1966). https://doi.org/10.1038/2121572b0
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1038/2121572b0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.
