Abstract
As reported by Lewis, Nyholm and Rodley (preceding communication), diphenylmethylarsine oxide (Ph2MeAsO) forms a series of complexes with the metal II perchlorates of manganese, iron, cobalt, nickel, copper and zinc. The magnetic properties of this series, together with their absorption spectra in the ultra-violet, visible and infra-red regions, are discussed by those authors. Since the structural implications of these physical properties were not entirely conclusive, we have undertaken a structure analysis of the cobalt compound by single crystal X-ray diffraction techniques.
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References
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PAULING, P., ROBERTSON, G. & RODLEY, G. Co-ordination of Transition Metals by the Perchlorate Ion: The Crystal Structure of Co(Ph2MeAsO)4(CI04)2. Nature 207, 73–74 (1965). https://doi.org/10.1038/207073a0
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DOI: https://doi.org/10.1038/207073a0
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