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Phase Studies Within the System ZrO2-MgO

Abstract

THE phase diagram for the system, ZrO2–MgO, was re-investigated by means of the quenching technique and a ribbon element diffractometer furnace. Duwez et al.1 had first established a tentative phase diagram for this system. Recently, Hinz and Dietzel2 tried to determine the phase boundaries of the cubic solid solution field. They claimed that 7 moles per cent of MgO is the lowest limit for the formation of single phase cubic solid solutions between 1,800° C and the melting point. Similar results were obtained by Stöcker3. However, it is very probable that in their experiments the specimens containing less than 7 moles per cent MgO had at least partly converted to the monoclinic phase during the quenching.

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References

  1. Duwez, P., Odell, F., and Brown, jun., F. H., J. Amer. Ceram. Soc., 35, 107 (1952).

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  2. Hinz, I., and Dietzel, A., Ber. Dtsch. Ker. Ges., 39, 530 (1962).

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  3. Stöcker, J. H., Ph.D. thesis Faculté de Science, Paris, 1960.

  4. Smith, D. K., and Cline, C. F., J. Amer. Ceram. Soc., 45, 249 (1962).

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  5. Büssem, W., Schusterius, C., and Ungewiss, A., Ber. Dtsch. Ker. Ges., 18, 433 (1937).

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VIECHNICKI, D., STUBICAN, V. Phase Studies Within the System ZrO2-MgO. Nature 206, 1251–1252 (1965). https://doi.org/10.1038/2061251a0

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