Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Spur Reactions in the Radiolysis of Liquid Aliphatic Hydrocarbons

Abstract

A CONTRAST between the radiation chemistry of water and that of liquid aliphatic hydrocarbons is that, in the former, interpretation of the system is made on the basis of models involving the concepts of tracks and spurs1, and that in the latter these concepts are much less frequently invoked2,3. (‘Hot’ atom, unimolecular and ‘cage’ reactions have been suggested and may occur within a spur, but it is reactions other than these that are primarily discussed here.)

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Allen, A. O., The Radiation Chemistry of Water and Aqueous Solutions (D. Van Nostrand Co., Inc., New York, 1962).

    Google Scholar 

  2. Dyne, P. J., and Fletcher, J. W., Canad. J. Chem., 38, 851 (1960).

    Article  CAS  Google Scholar 

  3. Hardwick, T. J., J. Phys. Chem., 65, 101 (1961).

    Article  CAS  Google Scholar 

  4. Magee, J. L., Ann. Rev. Phys. Chem., 12, 396 (1961).

    Article  ADS  Google Scholar 

  5. de Vries, A. E., and Allen, A. O., J. Phys. Chem., 63, 15 (1958).

    Google Scholar 

  6. Dyne, P. J., J. Phys. Chem., 66, 767 (1962).

    Article  CAS  Google Scholar 

  7. Dyne, P. J., and Stone, J. A., Canad. J. Chem., 39, 2381 (1961).

    Article  CAS  Google Scholar 

  8. Holroyd, R. A., J. Phys. Chem., 65, 1353 (1961).

    Article  Google Scholar 

  9. Burns, W. G., J. Phys. Chem., 65, 2261 (1961).

    Article  CAS  Google Scholar 

  10. Schuler, R. H., and Allen, A. O., J. Amer. Chem. Soc., 77, 507 (1955).

    Article  CAS  Google Scholar 

  11. Schuler, R. H., J. Phys. Chem., 63, 925 (1959).

    Article  CAS  Google Scholar 

  12. Burton, M., and Falconer, J. W. (to be published).

  13. Dyne, P. J., and Jenkinson, W. M., Canad. J. Chem., 38, 539 (1960).

    Article  CAS  Google Scholar 

  14. Nash, J. R., and Hamill, W. H., J. Phys. Chem., 66, 1097 (1962).

    Article  CAS  Google Scholar 

  15. Schuler, R. H., J. Phys. Chem., 61, 1472 (1957).

    Article  CAS  Google Scholar 

  16. Horner, P. J., and Swallow, A. J., J. Phys. Chem., 65, 953 (1961).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

FALCONER, J. Spur Reactions in the Radiolysis of Liquid Aliphatic Hydrocarbons. Nature 198, 985–986 (1963). https://doi.org/10.1038/198985a0

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/198985a0

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing