Abstract
IT has been shown previously that dipyridyl (dipy) complexes of cobalt and nickel are reduced at the dropping-mercury electrode with the formation of uni- and zero-valent complexes, respectively1,2. Further work led to the conclusion that iron(II)–dipyridyl complex is not reduced at the dropping mercury electrode and that the complex Mn(dipy)3 2+ is reduced with the formation of manganase(I) complex (unpublished results).
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References
Vlček, A. A., Nature, 180, 753 (1957).
Vlček, A. A., Z. Elektrochem., 61, 1014 (1957).
Hein, F., and Herzog, S., Z. anorg. Chem., 267, 337 (1952).
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VLČCEK, A. Polarographic Behaviour of Chromium-Dipyridyl Complexes. Nature 189, 393–394 (1961). https://doi.org/10.1038/189393b0
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DOI: https://doi.org/10.1038/189393b0
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