Abstract
SINCE the earliest observations1,2 on the cross-linking of organic polymers by ionizing radiation, much research has been devoted to this phenomenon, but there remains no generally accepted mechanism applicable to all polymers3. For polyethylene it has been proposed4 that linkages between molecules arise from three independent processes:
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References
Dole, M., Report of the fourth symposium on “Chemistry and Physics of Radiation Dosimetry”, Army Chemical Centre, Maryland, 112 (1950).
Charlesby, A., Proc. Roy. Soc., A, 215, 187 (1952).
Charlesby, A., and Swallow, A. J., “Ann. Rev. Phys. Chem.”, 10, 305 (1959).
Williams, T. F., and Dole, M., J. Amer. Chem. Soc., 81, 2919 (1959).
Stevenson, D. P., J. Phys. Chem., 61, 1453 (1957).
Weiss, J., J. Polymer Sci., 29, 425 (1958).
Lawton, E. J., Balwit, J. S., and Powell, R. S., J. Polymer Sci., 32, 257 (1958).
Dole, M., Milner, D. C., and Williams, T. F., J. Amer. Chem. Soc., 80, 1580 (1958).
Dole, M., and Williams, T. F., Disc. Farad. Soc., No. 27, 74 (1959).
Black, R. M., and Lyons, B. J., Proc. Roy. Soc., A, 253, 322 (1959).
Charlesby, A., J. Polymer Sci., 11, 513 (1953).
Williams, T. F., Ph.D., thesis, University of London (1960).
Kuzminsky, A. S., Nikitina, T. S., Zhuravskaya, E. V., Oksentievich, L. A., Sunitsa, L. L., and Vitushkin, N. I., P/2085. Second United Nations Conf. on Peaceful Uses of Atomic Energy, 29, 258 (1960).
Flory, P. J., “Principles of Polymer Chemistry”, Chap. 11, 432 (Cornell Univ. Press, Ithaca, New York, 1953).
Roberts, D. E., and Mandelkern, L., J. Amer. Chem. Soc., 80, 1289 (1958).
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WILLIAMS, T. Modes of Radiation-induced Cross-Linking in Hydrocarbon Polymers. Nature 186, 544–545 (1960). https://doi.org/10.1038/186544a0
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DOI: https://doi.org/10.1038/186544a0
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