Abstract
THE tensile strength of a liquid is defined as the maximum negative pressure (P) that a liquid in an isothermal metastable state can sustain before returning to a two-phase system. Mathematically, this might be expressed as the value of P at which (∂P/∂V)T = 0, where V represents the volume of the liquid at temperature T. According to Temperley1, if Van der Waals's equation of state be assumed to hold for a liquid and the condition that (∂P/∂V)T = 0 be applied, the tensile strength may be calculated. Benson and Gerjuoy2, in working with the reduced form of this equation, arrived at: where ϕ = V/Vc, θ = T/Tc, π = P/Pc and the subscript c stands for critical value, by applying the condition: Values may be assigned to θ and the resulting cubic in ϕ will give rise to a real root which may in turn be substituted in to give reduced values of the tensile strength.
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References
Temperley, H. N. V., Proc. Phys. Soc., 59, 199 (1947).
Benson, S. W., and Gerjuoy, E., J. Chem. Phys., 17, 914 (1949).
Misener, A. D., and Hedgcock, F. T., Nature, 171, 835 (1953).
Vincent, R. S., Proc. Phys. Soc., 53, 126 (1941).
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MISENER, A., HÉBERT, G. Tensile Strength of Liquid Helium II. Nature 177, 946–947 (1956). https://doi.org/10.1038/177946a0
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DOI: https://doi.org/10.1038/177946a0
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