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Relative Reactivities of Substituted Anthracenes towards the Addition of 2-Cyano-2-propyl Radicals

Abstract

2-CYANO-2-PROPYL radicals generated by thermal decomposition of azo-bisisobutyronitrile in benzene solution readily add on to the meso-positions of anthracene1 or substituted anthracenes2 to form substituted 9,10-dihydroanthracenes. The following-reactions take place (R = 2-cyano-2-propyl; A = anthracene):

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FARENHORST, E., KOOYMAN, E. Relative Reactivities of Substituted Anthracenes towards the Addition of 2-Cyano-2-propyl Radicals. Nature 175, 598–599 (1955). https://doi.org/10.1038/175598a0

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