Abstract
THE nature of the forces giving rise to the intra-crystalline swelling of montmorillonite has been several times discussed. The recent work of Bradley1 and of myself2,3,4 on the swelling caused by adsorption of organic liquids enables us to get a clearer view of the problem, because these liquids form well-defined complexes in which the influence of the exchangeable ions is less marked than with water.
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References
Bradley, W. F., J. Amer. Chem. Soc., 67, 975 (1945).
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MacEwan, D. M. C., Trans. Farad. Soc., 42, B, 226 (1946).
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Bangham, D. H., and Mosallam, S., Proc. Roy. Soc, A, 166, 558 (1938).
Verwey, E. J. W., and Overbeek, J. Th. G., "Theory of the Stability of Lyophobic Colloids" (Elsevier, 1948).
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Gieseking, J. E., Soil Sci., 47, 1 (1939); Ensminger, L. E., and Gieseking, J. E., ibid., 48, 467 (1939).
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MACEWAN, D. Adsorption by Montmorillonite, and its Relation to Surface Adsorption. Nature 162, 935–936 (1948). https://doi.org/10.1038/162935a0
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DOI: https://doi.org/10.1038/162935a0
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