Abstract
Two difficulties have commonly been experienced in the exploration of potential distributions in electrolytic tanks, when alternating current is used : (a) non-linear conduction due to polarization at the electrode surfaces1, which becomes serious at very low potential differences or currents, and (b) corrosion of the electrodes causing the conducting path to assume a leading power factor2, which increases with increasing current density. Both effects are greatly reduced by raising the working frequency ; but they are incompatible with one another if very fine probe electrodes are used. The effect of frequency on the non-linear conduction is illustrated in the accompanying diagram.
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References
Rollet, A. P., C.R. Acad. Sci., Paris, 185, 457 (1927).
Shipley and Goodeve, Trans. Amer. Electro-Chem. Soc., 52, 377 (1927).
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MAKAR, R., BOOTHROYD, A. & CHERRY, E. An Electrolytic Tank for Exploring Potential Field Distributions. Nature 161, 845–846 (1948). https://doi.org/10.1038/161845a0
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DOI: https://doi.org/10.1038/161845a0
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