Abstract
In a recent paper by Brautis1, an attempt is made to relate the differences in optical rotatory power of the respective alkyl halides and the differences in atomic dimensions of the halogens. The ratio of differences in specific rotation (D line) of the 2-halogenopentanes were found to be (Br, 41.6 – 42.6, Cl): (I, 46.68 – 41.6, Br), that is, – 0.86: + 5.08. Atomic dimension differences require (Br - Cl): (I – Br) = 17.1: 21.4, and on this basis the bromide should have a larger rotation than the chloride.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Rec. trav. chim., 65, 799 (1946).
Cf. Houssa, Kenyon and Phillips, J. Chem. Soc., 1700 (1929). Cow-drey, Hughes, Ingold, Masterman and Scott, J. Chem. Soc., 1252 (1937).
J. Chem. Soc., 848 (1945).
McKenzie and Clough, J. Chem. Soc., 103, 687 (1913).
J. Chem. Soc., 106, 848(1945); 741 (1946).
J. Biol. Chem., 127, 237(1939).
J. Chem. Soc., 236 (1944).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
GERRBARD, W., LESSING, W. Optical Rotatory Power and Atomic Dimension. Nature 160, 467–468 (1947). https://doi.org/10.1038/160467b0
Issue Date:
DOI: https://doi.org/10.1038/160467b0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.