Abstract
A number of attempts have been made to devise general methods for the synthesis of phenazines1,2,3; but in a series of researches carried out during 1945–46 we found that most of the well-known methods failed in the case of some di-alkoxyphenazines. On the other hand, comparatively good results were obtained using the little-known reaction of Waterman and Vivian4, which depends on the treatment of a 2-nitro-or 2:2′-dinitrodiphenylamine with an ‘Oxygen acceptor’ such as reduced iron, lead or charcoal at a high temperature. In simple cases the reaction presumably proceeds, as suggested by the original authors, through the elimination of oxygen and water, but in the case of the 2: 2′-dinitro derivatives the course of the condensation is more obscure.
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References
Clemo and Mcllwain, J. Chem. Soc., 1991 (1934).
Wrede and Strack, Z. physiol. Chem., 177, 177 (1928).
Tomlinson, J. Chem. Soc., 158 (1939).
Waterman and Vivian, U.S. Patent 2,292,808.
McCombie, Scarborough and Waters, J. Chem. Soc., 353 (1928).
Fischer and Hepp, Ber., 23, 8141 (1890).
Ullmann and Dieterle, Ber., 37, 24 (1904).
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SLACK, P., SLACK, R. Phenazines and Benzcinnolines. Nature 160, 437–438 (1947). https://doi.org/10.1038/160437a0
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DOI: https://doi.org/10.1038/160437a0
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