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Article
| Open AccessNon-thermal phonon dynamics and a quenched exciton condensate probed by surface-sensitive electron diffraction
The thermalization of acoustic phonons after photoexcitation is traced by electron pulses in TiSe2, and the excitonic contribution to the structural order parameter of the material’s charge density wave phase is quantified.
- Felix Kurtz
- , Tim N. Dauwe
- & Claus Ropers
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Article |
Solution-phase sample-averaged single-particle spectroscopy of quantum emitters with femtosecond resolution
Combining fluorescence correlation spectroscopy and ultrafast spectroscopy, the sample-averaged dynamics of defects are studied with single-particle sensitivity in two-dimensional hexagonal boron nitride heterogeneous emitters.
- Jiaojian Shi
- , Yuejun Shen
- & Aaron M. Lindenberg
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Article |
Effect of pre-intercalation on Li-ion diffusion mapped by topochemical single-crystal transformation and operando investigation
Pre-intercalation with alkali-metal ions is attractive for accessing higher reversible capacity and improved rate performance in Li-ion batteries. Topochemical single-crystal transformations in a tunnel-structured positive electrode are used to clarify the effect of pre-intercalation in modifying the host lattice and altering diffusion pathways.
- Yuting Luo
- , Joseph V. Handy
- & Sarbajit Banerjee
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Article
| Open AccessSpatially reconfigurable antiferromagnetic states in topologically rich free-standing nanomembranes
Topological antiferromagnetic states are generated and spatially reconfigured in free-standing crystalline membranes of haematite through strain design.
- Hariom Jani
- , Jack Harrison
- & Paolo G. Radaelli
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Article |
Compensating losses in polariton propagation with synthesized complex frequency excitation
Propagation losses have limited the practical use of polaritons in photonic applications. Here the authors demonstrate a substantial enhancement in the propagation distance of phonon polaritons, employing synthetic optical excitation of complex frequency with virtual gain synthesized by combining multiple real frequency measurements.
- Fuxin Guan
- , Xiangdong Guo
- & Shuang Zhang
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Article |
Local atomic stacking and symmetry in twisted graphene trilayers
The local layer alignment in a wide range of trilayer graphene structures has been extracted by interferometric four-dimensional scanning transmission electron microscopy, uncovering the complex picture of lattice reconstruction in twisted trilayers.
- Isaac M. Craig
- , Madeline Van Winkle
- & D. Kwabena Bediako
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Article
| Open AccessReal-time single-proton counting with transmissive perovskite nanocrystal scintillators
Current organic proton detectors have poor detection sensitivities due to low light yields and limited radiation toleration. Here the authors report a perovskite nanocrystal-based transmissive thin scintillator that can detect seven protons per second, enabled by radiative emission from biexcitons.
- Zhaohong Mi
- , Hongyu Bian
- & Xiaogang Liu
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Feature |
Observing deformation in situ
Marc Legros, Frédéric Mompiou and Daniel Caillard discuss the different aspects that influence the reproducibility and reliability of characterizations performed using in situ mechanical tests in transmission electron microscopes.
- Marc Legros
- , Frédéric Mompiou
- & Daniel Caillard
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Feature |
Lifting the fog in ferroelectric thin-film synthesis
Frustrated by reproducibility in electrical measurements on ferroelectric films, Lane Martin, Jon-Paul Maria and Darrell Schlom discuss tactics to reliably synthesize ‘good’ ferroelectric samples, especially in the search for superior materials and device heterostructures.
- Lane W. Martin
- , Jon-Paul Maria
- & Darrell G. Schlom
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Article |
Imaging moiré excited states with photocurrent tunnelling microscopy
The authors combine laser excitation and scanning tunnelling spectroscopy to visualize the electron and hole distributions in photoexcited moiré excitons in twisted bilayer WS2. This photocurrent tunnelling microscopy approach enables the study of photoexcited non-equilibrium moiré phenomena at atomic scales.
- Hongyuan Li
- , Ziyu Xiang
- & Feng Wang
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News & Views |
Imaging the twist of antiferromagnetic merons in a blood-red iron oxide
The antiferromagnetic material haematite, named for its blood-red colour, hosts swirling spin vortices termed merons. The rotation sense of such antiferromagnetic vortices has now been imaged in real space.
- Leonie Spitz
- & Max Hirschberger
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Article
| Open AccessRevealing emergent magnetic charge in an antiferromagnet with diamond quantum magnetometry
Diamond quantum magnetometry is utilized to directly read the vorticity of antiferromagnetic spin textures through coupled multi-polar emergent magnetic charge distributions.
- Anthony K. C. Tan
- , Hariom Jani
- & Mete Atatüre
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News & Views |
Designer quantum dot molecules and beyond
Quantum dots couple to form artificial molecules that allow for variable colour emission in response to an electric field.
- James Cassidy
- , Justin Ondry
- & Dmitri V. Talapin
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News & Views |
The hole truth
By tracking the electrochromic doping front, a hole-limited electrochemical doping mechanism is discovered in organic mixed ionic–electronic conductors.
- Ruiheng Wu
- , Dilara Meli
- & Jonathan Rivnay
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Large-scale optical characterization of solid-state quantum emitters
Employing a widefield cryogenic microscope to parallelize resonant spectroscopy, chip-scale automated optical characterization of solid-state quantum emitters is demonstrated.
- Madison Sutula
- , Ian Christen
- & Dirk R. Englund
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The exit of nanoparticles from solid tumours
Nanoparticle retention inside tumours has been associated with lymphatic vessel collapse. It is now shown that nanoparticles exit from solid tumours through lymphatic vessels in or surrounding the tumour by a nanoparticle-size-dependent mechanism.
- Luan N. M. Nguyen
- , Zachary P. Lin
- & Warren C. W. Chan
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Multislip-enabled morphing of all-inorganic perovskites
In situ tests show that all-inorganic lead halide perovskite micropillars can morph into distinct shapes without affecting their optoelectronic properties and bandgap, which provides insights into the plastic deformation of semiconductors and also shows their potential for manufacturing relevant devices.
- Xiaocui Li
- , You Meng
- & Yang Lu
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Electric-field-induced colour switching in colloidal quantum dot molecules at room temperature
Current quantum dot emitters are limited to small-spectral-range colour tuning accompanied by intensity reduction. Electric-field-induced reversible emission colour switching without intensity loss can be achieved on a single-particle level in quantum dot molecules with two coupled emission centres.
- Yonatan Ossia
- , Adar Levi
- & Uri Banin
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Comment |
Extra electron reflections in concentrated alloys do not necessitate short-range order
In many concentrated alloys of current interest, the observation of diffuse superlattice intensities by transmission electron microscopy has been attributed to chemical short-range order. We briefly review these findings and comment on the plausibility of widespread interpretations, noting the absence of expected peaks, conflicts with theoretical predictions, and the possibility of alternative explanations.
- Flynn Walsh
- , Mingwei Zhang
- & Mark Asta
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Perspective |
Sustainable electronic textiles towards scalable commercialization
The commercialization of electronic textile (e-textile) products requires balanced sustainability considerations. Here the authors propose an e-textile design framework involving repair, recycle, replacement and reduction that can unify environmental friendliness, market viability, supply-chain resilience and user experience quality.
- HaoTian Harvey Shi
- , Yifei Pan
- & Yan Yan Shery Huang
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Article
| Open AccessHole-limited electrochemical doping in conjugated polymers
Electrochemical doping is assumed to be limited by ion motion due to large mass in mixed ionic-electronic conductors. Here, the authors reveal in a typical polythiophene that electrochemical doping speeds are limited by poor hole transport at low doping levels, leading to much slower switching speeds than expected.
- Scott T. Keene
- , Joonatan E. M. Laulainen
- & George G. Malliaras
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Article
| Open AccessLight-induced hexatic state in a layered quantum material
The authors report the emergence of a transient hexatic state during laser-induced transformation between two charge-density wave (CDW) phases in a thin film of the CDW material 1T-TaS2.
- Till Domröse
- , Thomas Danz
- & Claus Ropers
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Letter
| Open AccessPicophotonic localization metrology beyond thermal fluctuations
The authors report subatomic precision in measuring the displacement of a nanowire. Such precision is achieved by employing deep-learning enabled analysis of single-shot scattering of topologically structured superoscillatory illumination.
- Tongjun Liu
- , Cheng-Hung Chi
- & Nikolay I. Zheludev
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News & Views |
Distinguishing atomic vibrations near point defects
Local vibrational modes at substitutional impurities in monolayer graphene are resolved with a sensitivity at the chemical bonding level, revealing the impacts of different chemical configurations and mass of impurity atoms on the defect-perturbed vibrational properties.
- Xingxu Yan
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Letter
| Open AccessProbing lithium mobility at a solid electrolyte surface
Understanding lithium dynamics in solid-state electrolytes used for Li-ion batteries can be challenging. Using nonlinear extreme-ultraviolet spectroscopies, a direct spectral signature of surface lithium ions showing a distinct blueshift relative to the bulk absorption spectra is observed in a prototypical solid-state electrolyte.
- Clarisse Woodahl
- , Sasawat Jamnuch
- & Michael Zuerch
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Article |
Scalable manufacturing of high-index atomic layer–polymer hybrid metasurfaces for metaphotonics in the visible
The authors propose a method for the scalable manufacturing of metalenses using deep-ultraviolet argon fluoride immersion lithography and wafer-scale nanoimprint lithography, opening a route towards their low-cost, high-throughput mass production.
- Joohoon Kim
- , Junhwa Seong
- & Junsuk Rho
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Single-atom vibrational spectroscopy with chemical-bonding sensitivity
Vibrational spectroscopy now allows for the exploration of lattice vibrational properties at the chemical-bond level, revealing the impact of chemical-bonding configurations and atomic mass on local phonon modes in graphene with a new level of sensitivity.
- Mingquan Xu
- , De-Liang Bao
- & Wu Zhou
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Article |
Tip-induced excitonic luminescence nanoscopy of an atomically resolved van der Waals heterostructure
Tip-induced excitonic luminescence nanoscopy of an atomically resolved van der Waals heterostructure.
- Luis E. Parra López
- , Anna Rosławska
- & Guillaume Schull
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Letter |
Observation of a massive phason in a charge-density-wave insulator
We report the observation of narrowband terahertz emission from a quasi-one-dimensional charge-density-wave insulator, (TaSe4)2I. The origin of the emitted radiation is interpreted as a phason that obtains mass due to the long-range Coulomb interaction.
- Soyeun Kim
- , Yinchuan Lv
- & Fahad Mahmood
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News & Views |
Ultrafast plasmonics shapes electron beams
By exploiting optical phase-modulation at complex surface plasmon polariton patterns, as well as energy-filtered imaging, femtosecond electron pulses are dynamically shaped in phase and amplitude.
- Armin Feist
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Article |
A multiscale ion diffusion framework sheds light on the diffusion–stability–hysteresis nexus in metal halide perovskites
This study identifies a fundamental link between slow-moving ions inside grains and fast-moving ions along grain boundaries in metal halide perovskites that governs their environmental stability and current–voltage responses.
- Masoud Ghasemi
- , Boyu Guo
- & Aram Amassian
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Article |
Tunable photon-induced spatial modulation of free electrons
On-demand electron wavefront shaping is desirable for applications from nanolithography to imaging. Here, the authors present tunable photon-induced spatial modulation of electrons through their interaction with externally controlled surface plasmon polaritons.
- Shai Tsesses
- , Raphael Dahan
- & Ido Kaminer
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News & Views |
Picturing charge carrier diffusion
Spectral shifts in transient photoluminescence measurements performed with a confocal microscope allow tracking of charge carrier mobilities in polycrystalline halide perovskites.
- Thomas Kirchartz
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Letter |
Planar thermal Hall effect of topological bosons in the Kitaev magnet α-RuCl3
The authors report a strongly temperature-dependent thermal conductivity at low temperature, consistent with topological bosonic modes in a Chern-insulator-like model.
- Peter Czajka
- , Tong Gao
- & N. P. Ong
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Efficient vertical charge transport in polycrystalline halide perovskites revealed by four-dimensional tracking of charge carriers
A discrepancy exists between the low diffusion coefficients and near-unity charge collection efficiencies achieved in practical halide perovskite solar cells. Here, the authors explain this through the discovery of strong heterogeneity in vertical charge diffusivities in a 3D perovskite film.
- Changsoon Cho
- , Sascha Feldmann
- & Neil C. Greenham
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Formation and impact of nanoscopic oriented phase domains in electrochemical crystalline electrodes
Electrochemical phase transformation in ion-insertion crystalline electrodes is accompanied by compositional and structural changes. The formation of oriented phase domains and the development of strain gradient is now mapped quantitatively during the electrochemical ion-insertion process.
- Wenxiang Chen
- , Xun Zhan
- & Qian Chen
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Article |
Ultrastrong nanotwinned titanium alloys through additive manufacturing
Laser additive manufacturing can be exploited to generate unique internally twinned nanoprecipitates in commercial titanium alloys, paving the way to fabricate ultrastrong metallic materials with intricate shapes for broad applications.
- Yuman Zhu
- , Kun Zhang
- & Aijun Huang
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Operando monitoring of single-particle kinetic state-of-charge heterogeneities and cracking in high-rate Li-ion anodes
Understanding the ion intercalation and degradation mechanisms occurring during realistic battery operation is crucial to developing high-rate battery electrodes. Operando optical scattering microscopy is now used to study single-particle kinetic state-of-charge heterogeneities and cracking in high-rate Li-ion anode materials.
- Alice J. Merryweather
- , Quentin Jacquet
- & Clare P. Grey
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Letter |
Scalable optical manufacture of dynamic structural colour in stretchable materials
Desired for optical sensing or visual communications, structural colour-changing materials are hindered by the lack of scalable manufacturing. Here, by adapting Lippmann photography, large-area manufacturing of colour patterns in photosensitive elastomers is realized.
- Benjamin Harvey Miller
- , Helen Liu
- & Mathias Kolle
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Article
| Open AccessUnconventional excitonic states with phonon sidebands in layered silicon diphosphide
Distinct electronic and optical properties emerge from quantum confinement in low-dimensional materials. Here, combining optical characterization and ab initio calculations, the authors report an unconventional excitonic state and bound phonon sideband in layered silicon diphosphide.
- Ling Zhou
- , Junwei Huang
- & Hongtao Yuan
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News & Views |
Bi-state switch in moiré stacking
Twisted monolayer–multilayer graphene superlattices present bi-stable reconstruction states, with reversible switch in-between and long-distance propagation triggered by local mechanical perturbation. This provides additional degrees of freedom for moiré engineering.
- Augusto Ghiotto
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News & Views |
Busting through quantum dot barriers
Early time transient absorption microscopy in quantum dot solids reveals anomalous exciton transport with multiple different temporal regimes within hundreds of femtoseconds after photoexcitation.
- Naomi S. Ginsberg
- & William A. Tisdale
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News & Views |
Self-assembly across scales
Coupling between nanoscale self-assembly and capillary pattern formation leads to ordered thin films with multiscale structure spanning six orders of magnitude.
- Kyle J. M. Bishop
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Article |
Harmonic acoustics for dynamic and selective particle manipulation
Precise manipulation of colloids and cells is desired for material and life sciences. However, such control remains challenging without material modifications. Here, the authors achieve reversible single-particle manipulation with subwavelength resolution and high throughput using harmonic acoustics.
- Shujie Yang
- , Zhenhua Tian
- & Tony Jun Huang
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News & Views |
Building skyrmions through frustration
Imaging the magnetic structure in non-centrosymmetric nanoparticles reveals the emergence of a new spin texture, the skyrmionic vortex, stabilized through a chiral geometric frustration.
- Shawn David Pollard
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Article |
Tomographic measurement of dielectric tensors at optical frequency
Measuring three-dimensional dielectric tensors is desired for applications in material and soft matter physics. Here, the authors use a tomographic approach and inversely solve the vectorial wave equation to directly reconstruct dielectric tensors of anisotropic structures.
- Seungwoo Shin
- , Jonghee Eun
- & YongKeun Park
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Geometrically stabilized skyrmionic vortex in FeGe tetrahedral nanoparticles
The real-space magnetic configurations of a zero-dimensional skyrmionic vortex structure is uncovered using electron holography and micromagnetic simulations.
- Kodai Niitsu
- , Yizhou Liu
- & Yoshinori Tokura