Article
|
Open Access
Featured
-
-
Article
| Open AccessAgriculture causes nitrate fertilization of remote alpine lakes
The long-range atmospheric transport and deposition of reactive nitrogen may be affected by human activities. Here, the authors use isotope data to constrain sources of reactive nitrogen to high elevation lakes in the Uinta Mountains, finding that the majority originates from distant agricultural activities.
- E. J. Hundey
- , S. D. Russell
- & K. A. Moser
-
Article
| Open AccessXUV excitation followed by ultrafast non-adiabatic relaxation in PAH molecules as a femto-astrochemistry experiment
Extreme UV light sources allow us to study the dynamics of excited molecular stets over remarkably short timeframes. Here, the authors probe polyaromatic hydrocarbons—large organic molecules—and show their electronic excitation and subsequent ultrafast relaxation.
- A. Marciniak
- , V. Despré
- & F. Lépine
-
Article
| Open AccessNanoparticles with photoinduced precipitation for the extraction of pollutants from water and soil
Nanoparticles can act as absorbent materials for environmental clean-up due to their high surface-to-volume ratio, but subsequent removal can be difficult. Here, the authors report nanoparticles that aggregate upon UV radiation, allowing them to absorb pollutants from water and subsequently be removed in the aggregated state.
- Ferdinand Brandl
- , Nicolas Bertrand
- & Robert Langer
-
Article
| Open AccessEvidence for methane in Martian meteorites
Extremophiles on Earth are known to respire methane, and the potential existence of methane on Mars indicates similar organisms could survive there. Here, the authors present data from Martian meteorites confirming the presence of methane, indicating that a habitat capable of supporting organisms exists on Mars.
- Nigel J. F. Blamey
- , John Parnell
- & Roberta L. Flemming
-
Article |
Transparent air filter for high-efficiency PM2.5 capture
Particulate matter pollution is a public health concern in industrialized and urban areas. Here, the authors control the surface chemistry and microstructure of filtration materials to fabricate effective and transparent air filters for the capture of PM2.5pollutants.
- Chong Liu
- , Po-Chun Hsu
- & Yi Cui
-
Article |
Geochemistry of silicate-rich rocks can curtail spreading of carbon dioxide in subsurface aquifers
Carbon sequestration will be vital in mitigating future climate change, and understanding how CO2 behaves in aquifers is important for developing technologies. Here, the authors suggest that silicate-rich rocks inhibit the transport of CO2, which may have consequences for future engineered storage facilities.
- S. S. S. Cardoso
- & J. T. H. Andres
-
Article |
Mercury nano-trap for effective and efficient removal of mercury(II) from aqueous solution
Decontamination of mercury pollution from fresh water is a serious environmental issue. Here, the authors report a porous organic polymer-based nano-trap, functionalized with mercury chelating groups, capable of efficient and rapid mercury removal from aqueous media.
- Baiyan Li
- , Yiming Zhang
- & Shengqian Ma
-
Article |
Terrestrial selenium distribution in China is potentially linked to monsoonal climate
Selenium deficiency is a major health problem, particularly in the selenium-poor belt in China, yet its distribution in the terrestrial environment is poorly understood. Here, the authors combine geochemical and palaeoclimate data and show that selenium distribution in China may be related to East Asian monsoon rainfall.
- Tim Blazina
- , Youbin Sun
- & Lenny H.E. Winkel
-
Article |
The crystallization water of gypsum rocks is a relevant water source for plants
Some minerals, such as gypsum, hold water in their crystalline structure. Palacio et al. show that shallow-rooted plants growing on gypsum are able to make use of this crystallization water, suggesting an alternative water source for plants under conditions of severe drought.
- Sara Palacio
- , José Azorín
- & Juan Pedro Ferrio
-
Article |
Roaming dynamics in radical addition–elimination reactions
Roaming dynamics have been shown to be important in unimolecular decompositions, but the relevance to bimolecular reactions has been less clear. Here, the authors study radical addition/elimination reactions and implicate a roaming transition state in a bimolecular reaction.
- Baptiste Joalland
- , Yuanyuan Shi
- & Alexander M. Mebel
-
Article |
Graphene etching on SiC grains as a path to interstellar polycyclic aromatic hydrocarbons formation
Although polycyclic aromatic hydrocarbons have been observed in interstellar space, their formation mechanism is still unclear. Here, Merino et al.present a proof-of-concept study that these molecules can form in a top-down route on a graphitized surface of silicon-carbide stardust.
- P. Merino
- , M. Švec
- & J.A. Martin-Gago
-
Article |
Anthropogenic radionuclides in atmospheric air over Switzerland during the last few decades
Plutonium and caesium radioisotopes have been injected into the atmosphere during nuclear weapon tests and via other anthropogenic sources. Alvarado et al. show that volcanic eruptions can redistribute those isotopes in the lower atmosphere, using the Eyjafjallajökull eruption as an example.
- J. A. Corcho Alvarado
- , P. Steinmann
- & P. Froidevaux
-
Article |
Mobile uranium(IV)-bearing colloids in a mining-impacted wetland
The radioactive element uranium tends to accumulate in wetland soils in the insoluble and immobile tetravalent form. Wang et al. show that uranium(IV) can associate with highly mobile organic- and iron(II)-bearing colloids and that its mobility in organic-rich environments may be severely underestimated.
- Yuheng Wang
- , Manon Frutschi
- & Rizlan Bernier-Latmani
-
Article |
Photochemical reflectance index as an indirect estimator of foliar isoprenoid emissions at the ecosystem level
Isoprene and monoterpenes, emitted by terrestrial plants, have an important role in both plant biology and environment, but they are poorly quantified at the ecosystem level. Peñuelas et al.show that the photochemical reflectance index can be used to indirectly estimate foliar isoprenoid emissions remotely.
- Josep Peñuelas
- , Giovanni Marino
- & Iolanda Filella
-
Article |
Oxygen consumption rates in subseafloor basaltic crust derived from a reaction transport model
Deep oceanic crust could host a wealth of microbial life, but biogeochemical reactions therein are poorly understood. Orcutt et al.combine measurements of sedimentary oxygen and pore water chemistry from basement crust with a reactive transport box model to shed light on oxygen consumption in basaltic crust.
- Beth N. Orcutt
- , C. Geoffrey Wheat
- & Wolfgang Bach
-
Article |
Nitrate formation from atmospheric nitrogen and oxygen photocatalysed by nano-sized titanium dioxide
Nitrate pollutants are known to contribute to a variety of environmental problems. Here, the authors suggest that nano-sized titanium dioxide, as used in numerous surface coatings, may catalyse the formation of nitrate via the photochemical reaction of atmospheric nitrogen and oxygen.
- Shi-Jie Yuan
- , Jie-Jie Chen
- & Han-Qing Yu
-
Article |
Hygro-responsive membranes for effective oil–water separation
Membrane-based technologies to separate oil–water mixtures are energy-intensive, suffer from fouling or cannot separate a wide range of mixtures. Now, a new membrane is reported that is superhydrophilic and superoleophobic, and can separate a range of oil–water mixtures with high efficiency, without an external energy source.
- Arun K. Kota
- , Gibum Kwon
- & Anish Tuteja
-
Article |
The oceanic biological pump modulates the atmospheric transport of persistent organic pollutants to the Arctic
Persistent organic pollutants can reach and pollute pristine environments, such as the Arctic Ocean, through atmospheric transport. This study shows that the oceanic biological pump can sequester atmospheric polychlorinated biphenyls, reducing the transport of pollutants to the Arctic Ocean.
- Cristóbal Galbán-Malagón
- , Naiara Berrojalbiz
- & Jordi Dachs
-
Article |
A complex multi-notch astronomical filter to suppress the bright infrared sky
The night sky viewed from Earth is very bright at infrared wavelengths due to atmospheric emission, making land-based astronomy difficult in this spectral region. Here, a photonic filter is demonstrated to suppress this unwanted light, opening new paths to infrared astronomy with current and future telescopes.
- J. Bland-Hawthorn
- , S.C. Ellis
- & C. Trinh