Abstract
The fabrication of multifunctional nanomaterials and their subsequent use for novel applications in various branches of nanotechnology has been under intense scrutiny. Particularly in the area of nanomechanics, the design of multicomponent nanostructures with an integrated multifunctionality would enable the construction of building blocks for nanoscale analogues of macroscopic objects. Here, we introduce a new class of flexible nanostructures: metallic nanorods with polyelectrolyte hinges, synthesized using layer-by-layer electrostatic self-assembly of oppositely charged polyelectrolytes on barcode metal nanorods followed by segment-selective chemical etching. Nanorods with hinges that consist of one polyelectrolyte bilayer display considerable flexibility, but with a greater number of bilayers the flexibility of the hinge is significantly reduced. Magnetically induced bending about the polymer hinge is illustrated through the incorporation of nickel segments into the barcodes and the application of an external fluctuating magnetic field.
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Acknowledgements
G.A.O. is the Government of Canada Research Chair. He is deeply indebted to the Natural Sciences and Engineering Research Council (NSERC) of Canada for financial support for this work. A.A. and T.M. thank NSERC for graduate scholarships in support of their research. The authors wish to thank L. Cademartiri for helpful discussions.
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A.A. developed the original concept. A.A. and S.F. designed the experiment. M.L.F. performed the experiments on one-hinged nanorods. T.M. performed the experiment on two-hinged nanorods, analysed the brownian bending motion and incorporated the magnetic segment into the hinged barcodes. N.Z. greatly assisted in the experiments required to complete the study. All authors co-wrote the paper.
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Mirkovic, T., Foo, M., Arsenault, A. et al. Hinged nanorods made using a chemical approach to flexible nanostructures. Nature Nanotech 2, 565–569 (2007). https://doi.org/10.1038/nnano.2007.250
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DOI: https://doi.org/10.1038/nnano.2007.250
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