Transition-metal carbenes and alkylidenes are sometimes considered similar species with subtly different bonding and reactivities. Investigations into scandium and yttrium carbenes have raised questions about our understanding — and definition — of these widely used compounds.
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Metal-Diazo Radicals of α-Carbonyl Diazomethanes
Scientific Reports Open Access 10 March 2016
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References
Rouhi, A. M. Chem. Eng. News 80, 29–33 (2002).
Mills, D. P., Soutar, L., Lewis, W., Blake, A. J. & Liddle, S. T. J. Am. Chem. Soc. 132, 14379–14381 (2010).
Fustier, M., Le Goff, X. F., Le Floch, P. & Mézailles, N. J. Am. Chem. Soc. 132, 13108–13110 (2010).
Fischer, E. O. & Maasböl, A. Angew. Chem. Int. Ed. Engl. 3, 580–581 (1964).
Elschenbroich, C. Organometallics 3rd edn 333–345 (Wiley-VCH, 2006).
Schrock, R. R. J. Am. Chem. Soc. 96, 6796–6797 (1974).
Tebbe, F. N., Parshall, G. W. & Reddy, G. S. J. Am. Chem. Soc. 100, 3611–3613 (1978).
Roper, W. R. & Gallop, M. A. Adv. Organomet. Chem. 25, 121–198 (1986).
Scott, J. & Mindiola, D. J. Dalton Trans. 8463–8472 (2009).
Giesbrecht, G. R. & Gordon, J. C. Dalton Trans. 2387–2393 (2004).
Lu, E., Li, Y. & Chen, Y. Chem. Commun. 46, 4469–4471 (2010).
Bailey, P. J. et al. Chem. Eur. J. 9, 4820–4828 (2003).
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Mindiola, D., Scott, J. Spot the difference. Nature Chem 3, 15–17 (2011). https://doi.org/10.1038/nchem.940
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DOI: https://doi.org/10.1038/nchem.940
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Metal-Diazo Radicals of α-Carbonyl Diazomethanes
Scientific Reports (2016)