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Polycyclic aromatics

On-surface molecular engineering

Rational synthesis of large polycyclic molecules is on its way. A bottom-up strategy for molecular assembly to tailor-make new molecules has been applied to fabricate nanographenes.

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Figure 1: Cyclohexa-o-p-o-p-o-p-phenylene (left) can be converted into tribenzocoronene (right) by means of a thermally induced, surface-assisted cyclodehydrogenation process.

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Martin-Gago, J. On-surface molecular engineering. Nature Chem 3, 11–12 (2011). https://doi.org/10.1038/nchem.923

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