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An X-ray structural study of cacoxenite, a mineral phosphate

Abstract

Cacoxenite1 is a widespread highly hydrated basic ferric oxyphosphate mineral distributed in gossans, iron-and manganese-bearing novaculites, and an occasional constituent of ferruginous soils and sediments. For long a troublesome aspect of mineralogic science and extensively investigated in the past, cacoxenite remained an enigma for lack of suitable material for X-ray diffraction single crystal study. We have now obtained a suitable specimen and report here that it has a framework structure containing enormous channels.

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Moore, P., Shen, J. An X-ray structural study of cacoxenite, a mineral phosphate. Nature 306, 356–358 (1983). https://doi.org/10.1038/306356a0

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