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Laser-induced chemistry

Abstract

Some 20 years ago the invention of lasers led to suggestions that the high-intensity monochromatic light that they produce might be used to bring about a new class of chemical interaction. Over the past 10 years this new chemistry has come of age.

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References

  1. Schawlow, A. L. Bell Lab. Rec., November, 403 (1960); Scient. Am. 204, 52 (1961).

    Google Scholar 

  2. Zewail, A. (ed.) Advances in Laser Chemistry (Springer, Berlin, 1978).

    Google Scholar 

  3. Ben-Shaul, A., Haas, Y., Kompa, K. L. & Levine, R. D. Lasers and Chemical Charge (Springer, Berlin, 1981).

    Book  Google Scholar 

  4. Cantrell, C. D., Freund, S. M. & Lyman, J. L. in Laser Handbook Vol. 3 (ed. Stitch, M. L.) 485 (North-Holland, Amsterdam, 1979).

    Google Scholar 

  5. Letokhov, V. S. Nonlinear Laser Chemistry (Springer, Berlin, 1983).

    Book  Google Scholar 

  6. Letokhov, V. S. & Moore, C. B. in Chemical and Biochemical Applications of Lasers Vol. 3 (ed. Moore, C. B.) 1 (Academic, New York, 1977).

    Book  Google Scholar 

  7. Letokhov, V. S. Nature 277, 605 (1979).

    Article  ADS  CAS  Google Scholar 

  8. Calvert, J. G. & Pitts, J. N. Jr Photochemistry (Wiley, New York, 1966).

    Google Scholar 

  9. Hall, R. T. & Pimental, G. C. J. chem. Phys. 38, 1889 (1963).

    Article  ADS  CAS  Google Scholar 

  10. Ambartzumian, R. V. & Letokhov, V. S. Appl. Opt. 11, 354 (1972).

    Article  ADS  CAS  Google Scholar 

  11. Letokhov, V. S. Science 180, 451 (1973).

    Article  ADS  CAS  Google Scholar 

  12. Merchant, V., Isenor, N. R., Hallsworth, R. S. & Richardson, M. C. Can. J. Phys. 51, 1281 (1973).

    Article  ADS  Google Scholar 

  13. Ambartzumian, R. V., Chekalin, N. V., Doljikov, V. S., Letokhov, V. S. & Ryabov, E. A. Chem. phys. Lett. 25, 515 (1974).

    Article  ADS  Google Scholar 

  14. Ambartzumian, R. V. & Letokhov, V. S. in Chemical and Biochemical Applications of Lasers Vol. 3 (ed. Moore, C. B.) 166 (Academic, New York, 1977).

    Google Scholar 

  15. Ambartzumian, R. V., Letokhov, V. S., Ryabov, E. A. & Chekalin, N. V. Pis'ma Zh. Eksp. Teor. Fiz. (Russian) 20, 597 (1974).

    Google Scholar 

  16. Brooks, P. R. & Hayes, E. F. Jr (eds). Am. chem. Soc. Symp. Ser. No. 56 (1977).

  17. Zare, R. N. & Bernstein, R. B. Phys. Today 33, 43 (1980).

    Article  CAS  Google Scholar 

  18. Solarz, R. W., Johnson, S. A. & Preston, R. H. Chem. phys. Lett. 57, 514 (1978).

    Article  ADS  CAS  Google Scholar 

  19. Baranovski, A. P. et al. Optical Sciences Vol. 3 (eds Mooradian, A., Jaeger, T. & Stokseth, P.) 108 (Springer, Berlin, 1976).

    Google Scholar 

  20. Stuke, M. & Schäfer, F. P. Chem. Phys. Lett. 48, 271 (1977).

    Article  ADS  CAS  Google Scholar 

  21. Stuke, M. & Marinero, E. E. Chem. Phys. Lett. 68, 28 (1979).

    Article  ADS  CAS  Google Scholar 

  22. Lau, A. M. F. Phys. Rev. A 13, 139 (1976); A 19, 1117 (1979).

    Article  ADS  CAS  Google Scholar 

  23. Hering, P., Brooks, P. R., Curl, R. F. Jr, Judson, S. & Lowe, R. S. Phys. Rev. Lett. 44, 687 (1980).

    Article  ADS  CAS  Google Scholar 

  24. Ehrlich, D. J., Osgood, R. M. Jr & Deutsch, T. F. IEEE J. Quant. Electr. QE-16, 1233 (1980).

    Article  ADS  Google Scholar 

  25. Rhodes, Ch. K. (ed.) Topics in Applied Physics Vol. 30 (Springer, Berlin, 1979).

  26. Malatesta, V., Willis, C. & Hackett, J. J. Am. chem. Soc. 103, 6781 (1981).

    Article  CAS  Google Scholar 

  27. Wolfrum, J., Kneba, M., Clough, P. & Schneider, M. FRG Patents 29 38 353.7 & 30 08 848.3.

  28. Kneba, M. & Wolfrum, J. J. phys. Chem. 83, 69 (1979).

    Article  CAS  Google Scholar 

  29. Kneba, M. & Wolfrum, J. Am. Rev. phys. Chem. 31, 47 (1980).

    Article  ADS  CAS  Google Scholar 

  30. Zewail, A. H. Phys. Today 33, 27 (1980).

    Article  CAS  Google Scholar 

  31. Reddy, K. V. & Berry, M. J. Chem. Phys. Lett. 66, 223 (1979).

    Article  ADS  CAS  Google Scholar 

  32. Bloembergen, N. & Yablonovitch, E. Phys. Today 83 (1978).

  33. Lee, Y. T. & Shen, Y. R. Phys. Today 52 (1980).

  34. Letokhov, V. S. & Makarov, A. A. Usp. Fiz. Nauk (Russian) 134, 45 (1981).

    Article  CAS  Google Scholar 

  35. Robinson, P. J. & Holbrook, K. A. Unimolecular Reactions (Wiley-Interscience, New York, 1972).

    Google Scholar 

  36. Bagratashvili, V. N. et al. Zh. eksp. teor. Fiz. 77, 2238 (1979); Soviet Phys. JETP 56, 1075 (1979).

    CAS  Google Scholar 

  37. Bagratashvili, V. N. et al. Zh. eksp. teor. Fiz. 80, 1008 1981; Soviet Phys. JETP 53, 512 (1981); Opt. Lett. 6, 148 (1981).

    ADS  CAS  Google Scholar 

  38. Danen, W. C., Koster, D. F. & Zitter, R. N. J. Am. chem. Soc. 101, 15 4281 (1979).

    Article  CAS  Google Scholar 

  39. Morrison, R. J. S., Loring, R. F., Farley, R. L. & Grant, E. R. J. chem. Phys. 75, 148 (1981).

    Article  ADS  CAS  Google Scholar 

  40. Rossi, M., Barker, J. R. & Golden, D. M. J. chem. Phys. 76, 406 (1982).

    Article  ADS  CAS  Google Scholar 

  41. Danen, W. C., Rio, V. C. & Setser, D. W. J. Am. chem. Soc. 104, 5431 (1982); 5440 (1982).

    Article  CAS  Google Scholar 

  42. Zhang, F., Francisco, J. S. & Steinfeld, J. I. J. chem. Phys. 86, 2402 (1982).

    Article  CAS  Google Scholar 

  43. Stuke, M., Sumida, D. & Wittig, C. J. chem. Phys. 86, 438 (1982).

    Article  CAS  Google Scholar 

  44. Jasinski, J. M., Rosenfeld, R. N., Meyer, F. K. & Brauman, J. I. J. Am. chem. Soc. 104, 652 (1982).

    Article  CAS  Google Scholar 

  45. Schulz, P. A. et al. A. Rev. phys. Chem. 30, 379 (1979).

    Article  ADS  CAS  Google Scholar 

  46. Bagratashvili, V. N. et al. Pis'ma Zh. eksp. teor. Fiz. (Russian) 35, 155 (1982).

    CAS  Google Scholar 

  47. Bagratashvili, V. N., Kuzmin, M. V., Letokhov, V. S. & Shibanov, A. N. Pis'ma Zh. eksp. teor. Fiz. (Russian) 37, 92 (1983).

    CAS  Google Scholar 

  48. Marcus, R. A. in Picosecond Phenomena III (eds Eizenthal, K. B., Hochstrasser, R. M., Kaiser, W. & Laubereau, A.) (Springer, Berlin, 1982).

    Google Scholar 

  49. Clark, J. H., Leary, K. M., Loree, T. R. & Harding, L. B. in Advances in Laser Chemistry (ed. Zewal, A.) 74 (Springer, Berlin, 1978).

    Book  Google Scholar 

  50. Bagratashvili, V. N., Burimov, V. N., Kuzmin, M. V., Letokhov, V. S. & Sviridov, A. P. Laser Chem. 1(3), 133 (1983).

    Article  CAS  Google Scholar 

  51. Bagratashvili, V. N., Kuzmin, M. V. & Letokhov, V. S. Laser Chem. 1(6) (in the press).

  52. Letokhov, V. S. in Tunable Lasers and Applications (eds Mooradian, A., Jaeger, T. & Stokseth, P.) 122 (Springer, Berlin, 1976).

    Book  Google Scholar 

  53. Antonov, V. S. & Letokhov, V. S. Appl. Phys. 24, 89 (1981).

    Article  ADS  CAS  Google Scholar 

  54. Gedanken, A., Robin, M. B. & Kneubler, N. A. J. phys. Chem. 86, 4096 (1982).

    Article  CAS  Google Scholar 

  55. Lichtin, D. A., Zandee, L., Bernstein, R. B. in Lasers and Chemical Analysis (eds Hieftje, G. M., Lytle, F. E. & Travis, J. C.) 1 (Humana, Clifton, 1980).

    Google Scholar 

  56. Lewis, G. & Kasha, M. J. Am. chem. Soc. 66, 2100 (1944).

    Article  CAS  Google Scholar 

  57. Kryukov, P. G. et al. Chem. phys. Lett. 61, 375 (1979).

    Article  ADS  CAS  Google Scholar 

  58. Angelov, D. A., Kryukov, P. G., Letokhov, V. S., Nikigosyan, D. N. & Oraevsky, A. A. Kvant. Elektron. (Russian) 8, 595 (1981).

    CAS  Google Scholar 

  59. Karu, T. I., Letokhov, V. S., Kryukov, P. G., Matveetz, Yu. A. & Semchishen, V. A. Appl. Phys. 24, 245 (1981).

    Article  ADS  CAS  Google Scholar 

  60. Yokoyamu, K., Nakamura, J., Koboyashi, T. & Nagakura, S. Bull. chem. Soc. Jap. 53, 3474 (1980).

    Article  Google Scholar 

  61. Andreoni, A., Cubeddu, R., De Silvestri, S., Laporta, P. & Svelto, O. Chem. phys. Lett. 88, 37 (1982).

    Article  ADS  CAS  Google Scholar 

  62. Bagdasarian, Kh. S. Two-Photon Photochemistry (Russian) (Science, Moscow, 1976).

    Google Scholar 

  63. Letokhov, V. S., Matveetz, Yu. A., Semchishen, V. A. & Khoroshilova, E. V. Appl. Phys. B 26, 243 (1981).

    Article  Google Scholar 

  64. Brackmann, U. & Schäfer, F. P. Chem. phys. Lett. 87, 579 (1982).

    Article  ADS  CAS  Google Scholar 

  65. Kuzmina, N. P., Khoroshilova, E. V., Letokhov, V. S. & Matveetz, Yu. A. Appl. Phys. B31, 195 (1983).

    Article  Google Scholar 

  66. Pitts, J. N. et al. J. Am. chem. Soc. 81, 1068 (1959).

    Article  CAS  Google Scholar 

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Letokhov, V. Laser-induced chemistry. Nature 305, 103–108 (1983). https://doi.org/10.1038/305103a0

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