Abstract
The concentrations of nitrate and ammonium ion in rainfall have an important effect on precipitation pH. We have collected sets of rainfall analyses from non-urban sites in North America and western Europe, which start from last century, and we show here that there is a marked increase in the annual deposit of nitrate ion compared with relatively stable levels of ammonium ion deposit. The increase apparent in the data from the US parallels the increases in nitrogen oxide emissions from combustion processes and is large enough for the nitrate ion to contribute almost as much to the acidity of rainfall as the sulphate ion.
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References
Brimblecombe, P. & Pitman, J. I. Tellus 32, 261–267 (1980).
Russell, E. J. & Richards, E. H. J. agric. Soc. 9, 309–337 (1919).
Liebig, J. Chemistry and its Applications to Agriculture and Physiology 3rd edn (Taylor and Walton, London, 1843).
Soderlund, R. & Svensson, B. H. SCOPE 7, 27–73 (1976).
Miller, N. H. J. J. agric. Sci. 1, 280–303 (1905).
Galloway, J. N. & Whelpdale, D. M. Atmos. Envir. 14, 409–417 (1980).
Hammond, A. L., Metz, W. D. & Maugh, T. H. II Energy and the Future (American Association for the Advancement of Science, 1973).
Mulbhaier, J. L. in Solid Residential Fuels (eds. Cooper, J. A. & Malek, D.) 164–187 (Oregon Graduate Centre, 1982).
Perkins, H. C. Air Pollution (McGraw-Hill, New York, 1974).
Wong, C. S. Science 200, 197–200 (1978).
Stedman, D. H. & Shetter, R. E. Adv. Envir. Sci. Technol (in the press).
Robinson, E. & Robbins, R. C. Air Pollut. Control Ass. J. 20, 303 (1970).
Robinson, E. & Robbins, R. C. in (ed. Singer, S. F.) The Changing Global Environment 50–64 (Springer, New York, 1970).
Charlson, R. J. & Rodhe, H. Nature 295, 683–685 (1982).
Martin, A. & Barber, F. R. CEGB (MR) Rural Rain Sampling Sites: Monthly Mean Concentration Values 1975-1980 (CEGB MID/SSD/81/0046/M, 1981).
Bach, W. Rev. Geophys. Space Phys. 14, 429–474 (1976).
Collinson, R. C. & Mensching, J. E. New York St. agric. exp. Stat. tech. Bull. No. 193 (1932).
Failyer, G. H. & Willard, J. T. 2nd Ann. Rep. Kansas agric. Stat. 132–132 (1889).
Freeman, V. F. J. Am. Soc. Agron. 16, 356–8 (1924).
Likens, G. E. Biogeochemistry of a Forested Ecosystem (Springer, Berlin, 1977).
Mooers, C. A., McIntyre, W. H. & Young, J. B. Univ. Tennessee agric. exp. Stat. Bull. No. 138 (1927).
Shutt, F. T. Proc. Trans. R. Soc. Can. 4, 55–59 (1910).
Shutt, F. T. Proc. Trans. R. Soc. Can. 8, 83–87 (1914).
Shutt, F. T. & Dorrance, R. L. Proc. Trans. R. Soc. Can. 11, 63–67, (1917).
Shutt, F. T. & Medley, B. Proc. Trans. R. Soc. Can. 19, 1–10 (1925).
Wilson, B. D. J. Am. Soc. Agron. 18, 1208–1212 (1926).
Cavender, J. H., Kircher, D. S. & Hoffman, A. J. US EPA Publ. No. AP-115 (1973).
Clark, T. L. Atmos. Envir. 14, 960–961 (1980).
Wahl, E. W. & Lawson, T. L. Mon. Weath. Rev. 98, 259–265 (1970).
Tellus 8, 112 (1956).
Erikson, E. Tellus 4, 215–232 (1952).
Jenkinson, D. S. Rothamsted Exptl Stat Rept. 1976, 103–109 (1977).
Dennington, V. N. & Chadwick, M. J. J. appl. Ecol. 15, 303–315 (1978).
White, E., Starkey, R. S. & Saunders, M. J. J. Appl. Ecol. 8, 743–749 (1971).
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Brimblecombe, P., Stedman, D. Historical evidence for a dramatic increase in the nitrate component of acid rain. Nature 298, 460–462 (1982). https://doi.org/10.1038/298460a0
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DOI: https://doi.org/10.1038/298460a0
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