Abstract
In the past five years, glass formation has been observed in many chemical systems involving zirconium tetrafluoride1–5. These ionic glasses were unexpected as no theory of glass formation had predicted their occurrence. Most common glasses can be explained by the Zachariazen theory6 which gives criteria for vitreous structures with highly directed three-dimensional bond arrays, according to energy and kinetic considerations. However, the theory does not encompass some new amorphous systems such as amorphous germanium or the new ionic glasses. I review here the structural and energetic conditions for glass formation in ionic systems with particular reference to fluoride glasses.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Poulain, M., Poulain, M., Lucas, J. & Brun, P. Mater. Res. Bull. 10, 243 (1975).
Poulain, M., Chanthanasinh, M. & Lucas, J. Mater. Res. Bull. 12, 151 (1977).
Lucas, J. et al. J. Non-Cryst. Sol. 27, 273 (1978).
Aliaga, N., Fonteneau, G. & Lucas, J. Ann. Chim. Sci. Mater. 3, 51 (1978).
Lecoq, A. & Poulain, M. J. NonCryst. Sol. 34, 101 (1979); 41, 209 (1980); Verres Réfract 34, 333 (1980).
Zachariasen, W. H. J. Am. chem. Soc 545, 3480 (1932).
Willis, B. T. M. Proc. Br. ceram. Soc. 1, 9 (1964).
Cheetham, A. K., Fender, B. E. F., Steele, D., Taylor, R. I. & Willis, B. T. M. Solid State Commun. 8, 171 (1970).
Mann, A. W. & Bevan, D. J. M. J. Solid State Chem. 5, 410 (1972).
Tofield, B. C., Poulain, M. & Lucas, J. J. Solid State Chem. 27, 163 (1979).
Poulain, M., Poulain, M. & Lucas, J. J. Rev. Chim. Min. 12, 9 (1975).
Poulain, M. & Lucas, J. Verres Réfract. 32, 505 (1978); The Rare Earths in Modern Science Technology (Plenum, New York, 1978).
Tosi, M. Solid State Phys. 16, 1 (1964).
Miranday, J. P., Jacoboni, C. & De Pape R. Rev. Chim. Min. 16, 277 (1979); J. Non-Cryst. Sol. 43, 393 (1981).
Poulain, M., Poulain, M. & Maze, G. French Patent 80-06088; European patent 81-400409.0.
Fonteneau, G., Lahaie, F. & Lucas, J. Mater. Res. Bull. 15, 1143 (1980).
Stokowski, S. E., Saroyan, R. A. & Weber, M. J. Nd Doped Laser Glass Spectroscopic and Physical Properties Rep. M-095, (Lawrence Livermore Laboratory, 1978).
Rawson, H. Inorganic Glass Forming Systems (Academic, London, 1967).
Baldwin, C. M., Almeida, R. M. & Mackenzie, J. D. J. Non-Cryst. Sol. 43, 309 (1981).
Drexhage, M. G., Moynihan, C. T. & Saleh, M. Mater. Res. Bull. 15, 213 (1980).
Lucas, J., Slim, H. & Fonteneau, G. J. Non-Cryst. Sol. 44, 31 (1981).
Poulain, M., Poulain, M. & Matecki, M. Mater. Res. Bull. 16, 555 (1981); 16 (in the press).
Angell, C. A. & Ziegler, D. C. Mater. Res. Bull. 16, 279 (1981).
Shannon, R. D. Acta crystallogr. A32 751 (1976).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Poulain, M. Glass formation in ionic systems. Nature 293, 279–280 (1981). https://doi.org/10.1038/293279a0
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1038/293279a0
This article is cited by
-
Anomalous properties of chloroborosilicate glasses in the K2O–BaO–Al2O3–B2O3–SiO2–BaCl2 system
Bulletin of Materials Science (2015)
-
Evidence of Coordinate Field Index Influence on Upconversion Properties in Er3+ Doped Tellurite Glasses
Journal of Fluorescence (2006)
-
Evaluation of the stability of substituted InF3 glasses by differential thermal analysis
Journal of thermal analysis (1997)
-
Nitride glasses obtained by high-pressure synthesis
Nature (1994)
-
Rubber state of ionic fluorozirconate glasse
Nature (1987)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.