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Saturated platelets are new intermediates in hydrocarbon pyrolysis and carbon formation

Abstract

Formation of solid carbon during pyrolysis of gaseous hydrocarbons may involve ‘saturated platelet’ intermediates.

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References

  1. Gaydon, A. G. & Wolfhard, H. G. Flames (3rd edn) (Chapman & Hall, London, 1970).

    Google Scholar 

  2. Palmer, H. B. & Cullis, C. F. in Chemistry and Physics of Carbon 1, (ed. Walker, P. L.) 265–325 (Arnold, London, 1965).

    Google Scholar 

  3. Porter, G. in Combustion Researches and Reviews 1955 108–124 (6th and 7th AGARD Combustion Panel Meetings, 1954) (Butterworths, London, 1955).

    Google Scholar 

  4. Porter, G. 4th Int. Symp. Combustion 248–252 (Williams and Wilkins, Baltimore, 1953).

    Google Scholar 

  5. Parker, W. G. & Wolfhard, H. G. J. chem. Soc. 153, 2038–2049 (1950).

    Article  Google Scholar 

  6. Thompkins, E. E. & Long, R. 12th Int. Symp. Combustion 625–634 (Combustion Institute, Pit sburgh, 1969).

    Google Scholar 

  7. Homann, K. H. & Wagner, H. G. 11th Int. Symp. Combustion 371–379 (Combustion Institute, Pittsburgh, 1967).

    Google Scholar 

  8. Morozova, G. A., Avarbé, R. G., Kapralov, V. K. & Shpak, V. S. Akad. Nauk SSSR Dokl. Chem. Tech. Sect. 221, 46–49 (1975).

    Google Scholar 

  9. Johnson, G. L. & Anderson, R. C. Proc. 5th Biennial Conf. Carbon. Buffalo 1, 395–405 (American Carbon Society, Pennsylvania State University, 1962).

    CAS  Google Scholar 

  10. Wersborg, B. L., Fox, L. K. & Howard, J. B. Combust. Flame, 24, 1–10 (1975).

    Article  CAS  Google Scholar 

  11. Prado, G. thesis, Centre Universitaire du Haut-Rhin et Universite Louis-Pasteur de Strasbourg (1972).

  12. Detz, C. M. Combust. Flame 26, 45–55 (1976).

    Article  CAS  Google Scholar 

  13. Bauer, S. H. 10th Int. Symp. Combustion, 511 (Combustion Institute, Pittsburgh, 1965).

  14. Silcocks, C. G. Proc. R. Soc. A242, 411–429 (1957).

    ADS  CAS  Google Scholar 

  15. Back, M. H. in The Mechanisms of Pyrolysis, Oxidation and Burning of Organic Materials (ed. Wall, L. A.), N.B.S. Special Publ. 357, 17–31 (U.S. Government Printing Office, Washington, 1972).

    Google Scholar 

  16. Benson, S. W. Thermochemical Kinetics, 117 (Wiley, New York, 1968).

  17. Graham, S. C., Homer, J. B. & Rosenfeld, J. L. J. Proc. R. Soc. A344, 259–285 (1975).

    Article  ADS  CAS  Google Scholar 

  18. Lahaye, J., Prado, G. & Donnet, J. B. Carbon 12, 27–35 (1974).

    Article  CAS  Google Scholar 

  19. Egloff, G. Physical Constants of Hydrocarbons 2, 294 (Reinhold, New York, 1940).

    Google Scholar 

  20. Fitzer, E., Mueller, K. & Schaefer, W. in Chemistry and Physics of Carbon (ed. Walker, P. L.) 7, 304 (Marcel Dekker, New York, 1971).

    Google Scholar 

  21. Place, E. R. & Weinberg, F. J. 11th Int. Symp. Combustion, 245–255 (Combustion Institute, Pittsburgh, 1967).

    Google Scholar 

  22. Miller, W. J. 11th Int. Symp. Combustion, 252–254 (Combustion Institute, Pittsburgh, 1967).

  23. Wersborg, B. L., Yeung, A. C. & Howard, J. B. Concentration and Mass Distribution of Charged Species in Sooting Flames, Project Squid Tech. Rep. MIT-85-PU (June 1974).

    Google Scholar 

  24. Howard, J. B., Wersborg, B. L. & Williams, G. C. Faraday Symp. Chem. Soc. no. 7, 109–119 (1973).

    Article  Google Scholar 

  25. Palmer, H. B. & Seery, D. J. A. Rev. Phys. Chem. 24, 253 (1973).

    Article  Google Scholar 

  26. Abrahamson, J. & Kennedy, E. R. 12th Biennial Conf. Carbon. Pittsburgh, 1975, (extended abstracts) 169–170 (American Carbon Society, Pennsylvania State University, 1975).

    Google Scholar 

  27. Bowser, R. J. & Weinberg, F. J. Combust. Flame (in the press).

  28. Streitwieser, A. J. Am. chem. Soc. 82, 4123–4135 (1960).

    Article  CAS  Google Scholar 

  29. Pople, J. A. J. Mass Spec. Ion Phys. 19, 89–106 (1976).

    Article  ADS  CAS  Google Scholar 

  30. Hughes, B. M., Lifshitz, C. & Tiernan, T. O. J. Chem. Phys. 59, 3162–3181 (1973).

    Article  ADS  CAS  Google Scholar 

  31. Miller, W. J. 11th Int. Symp. Combustion 311–320 (Combustion Institute, Pittsburgh, 1967).

  32. Feugier, A. & Van Tiggelen, A. 10th Int. Symp. Combustion, 621–623 (Combusttion Institute, Pittsburgh, 1965).

  33. Page, F. M. & Goode, G. C. Negative Ions and the Magnetron, 139 (Wiley–Interscience, New York, 1969).

    Google Scholar 

  34. Dillard, J. G. Chem. Rev. 73, 636 (1973).

    Article  Google Scholar 

  35. Fontijn, A. & Miller, W. J. 10th Int. Symp. Combustion, 623–624 (Combustion Institute, Pittsburgh, 1965).

  36. Kotani, M. and Akamatu, H. Discuss. Faraday. Soc. No. 51, 94–101 (1971).

  37. Ban, L. L. & Hess, W. M. Current Progress in the Study of Carbon Black Microstructure and General Morphology in Colloques internalionaux du CNRS. No. 231 81–115 (CNRS, Le Bischenberg-Obernai, 1973).

    Google Scholar 

  38. Howard, J. B. in 12th Int. Symp. Combustion, 877–887 (Combustion Institute, Pittsburgh, 1969).

    Google Scholar 

  39. Slotboom, H. W. & Penninger, J. M. L. Ind. Engng Chem. Process Des. Develop. 13, 296–299 (1974).

    Article  CAS  Google Scholar 

  40. Lobo, L. S. & Trimm, D. L. Prog. Vac. Microbal. Tech. 2, 1–8 (1973).

    CAS  Google Scholar 

  41. Cullis, C. F., Read, I. A. & Trimm, D. L. 11th Int. Symp. Combust. 391–397 (Combustion Institute, Pittsburgh, 1966).

  42. Plummer, E. W. in Interactions on Metal Surfaces (ed Gomer, R.) 214–223, Topics in Applied Physics, 4, (Springer-Verlag, Berlin, 1975).

    Google Scholar 

  43. Paál, Z., Fryer, J. R. & Thomson, S. J. in Symp. Mechanisms of Hydrocarbon Reactions, 5–7 June 1973, Siòfok, Hungary, (eds Márta, F. & Kallo, D.) 137–150 (Elsevier, Amsterdam, 1975).

    Google Scholar 

  44. Chakrabartty, S. K. & Kretschmer, H. O. Fuel 53, 132–135 (1974).

    Article  CAS  Google Scholar 

  45. Chakrabartty, S. K. & Berkowitz, N. Fuel 53, 240–245 (1974).

    Article  CAS  Google Scholar 

  46. Dovesi, R., Pisani, C., Ricca, F. & Roetti, C. J. chem. Phys. 65, 4116–4120 (1976).

    Article  ADS  CAS  Google Scholar 

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Abrahamson, J. Saturated platelets are new intermediates in hydrocarbon pyrolysis and carbon formation. Nature 266, 323–327 (1977). https://doi.org/10.1038/266323a0

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