Abstract
As usually stated, the second law of thermodynamics is asymmetric under time reversal, and is thus not compatible with a microscopic mechanics symmetric under time reversal. In its most popular form, the second law states that the entropy of a closed system tends to increase. Attempts to derive this from time-symmetric physical laws are self-defeating because any argument which leads to increasing entropy may be time reversed to produce an equally valid argument leading to decreasing entropy. Yet irreversibility is a fact of life. This is Loschmidt's paradox1.
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References
Loschmidt, J., S.B. Akad. Wiss. Wein, 73, 139 (1876).
Penrose, O., and Percival, I. C., Proc. Phys. Soc., 79, 606 (1962).
Landau, L. D., and Lifshitz, E. M., Statistical Physics, 28 (Pergamon Press, Oxford, 1969).
Landsberg, P. T., Studium Generate, 23, 1108 (1970).
Proc. Intern. Conf. Thermodynamics, Cardiff, 1970 (edit. by Landsberg, P. T.) (Butterworths, London, 1970).
Reichenbach, H., The Direction of Time (Univ. of California Press, Berkeley, 1956).
The Nature of Time (edit. by Gold, T.) (Cornell Univ. Press, 1967).
Boltzmann, L., Lectures on Gas Theory, section 90 (Univ. of California Press, 1964).
Landsberg, P. T., Thermodynamics, 82 (Interscience, New York, 1961).
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HILLEL, A. Alternative Statement of the Second Law of Thermodynamics. Nature 242, 456–457 (1973). https://doi.org/10.1038/242456a0
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DOI: https://doi.org/10.1038/242456a0
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