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Alternative Statement of the Second Law of Thermodynamics

Abstract

As usually stated, the second law of thermodynamics is asymmetric under time reversal, and is thus not compatible with a microscopic mechanics symmetric under time reversal. In its most popular form, the second law states that the entropy of a closed system tends to increase. Attempts to derive this from time-symmetric physical laws are self-defeating because any argument which leads to increasing entropy may be time reversed to produce an equally valid argument leading to decreasing entropy. Yet irreversibility is a fact of life. This is Loschmidt's paradox1.

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References

  1. Loschmidt, J., S.B. Akad. Wiss. Wein, 73, 139 (1876).

    Google Scholar 

  2. Penrose, O., and Percival, I. C., Proc. Phys. Soc., 79, 606 (1962).

    Article  ADS  Google Scholar 

  3. Landau, L. D., and Lifshitz, E. M., Statistical Physics, 28 (Pergamon Press, Oxford, 1969).

    Google Scholar 

  4. Landsberg, P. T., Studium Generate, 23, 1108 (1970).

    CAS  Google Scholar 

  5. Proc. Intern. Conf. Thermodynamics, Cardiff, 1970 (edit. by Landsberg, P. T.) (Butterworths, London, 1970).

  6. Reichenbach, H., The Direction of Time (Univ. of California Press, Berkeley, 1956).

    Book  Google Scholar 

  7. The Nature of Time (edit. by Gold, T.) (Cornell Univ. Press, 1967).

  8. Boltzmann, L., Lectures on Gas Theory, section 90 (Univ. of California Press, 1964).

    Book  Google Scholar 

  9. Landsberg, P. T., Thermodynamics, 82 (Interscience, New York, 1961).

    Google Scholar 

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HILLEL, A. Alternative Statement of the Second Law of Thermodynamics. Nature 242, 456–457 (1973). https://doi.org/10.1038/242456a0

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