Abstract
THE accuracy of the unperturbed frequency of the hydrogen maser is limited by the uncertainty of the wall shift caused by the storage bulb coating1. Different samples of nominally the same material have been found to give different shifts2 and so it seems that a frequency determination should include an independent measurement of wall shift. The results of such determinations3–7, however, have a spread of 0.018 Hz which is large compared with the potential accuracy of the maser. The wall shift depends on the number of bounces of the atoms on the wall of the bulb and for a spherical bulb can be expressed as K/D where K is a constant for a particular coating material and D is the diameter of the bulb. If measurements are made with bulbs of different size and the frequency is plotted against I/D), the true frequency is that corresponding to infinite bulb size, that is 1/D = 0, and the slope of the line gives the constant K. The range of bulb sizes that can be used is limited by practical considerations and there is therefore an extrapolation error in addition to the error of measurement. This extrapolation error can be reduced by making measurements with two different coating materials and making the assumption that the values should coincide at 1/D = 0.
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ESSEN, L., DONALDSON, R., BANGHAM, M. et al. Frequency of the Hydrogen Maser. Nature 229, 110–111 (1971). https://doi.org/10.1038/229110a0
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DOI: https://doi.org/10.1038/229110a0
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