Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Anodic Reactions of the Hydrogen Electrode

Abstract

EXTENSIVE studies have been made of the cathodic reactions of the hydrogen electrode (see reviews1,2) but relatively few observations have been made in anodic conditions3–5. One reason why the anodic reactions of the hydrogen electrode received little attention was that hydrogen electrodes which would support substantial anodic currents were not available. More recently, however, the interest in fuel cells has stimulated the development of electrodes that could maintain large currents in these conditions and as a result the anodic properties of the hydrogen electrode have been elucidated.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Hills, G. J., and Ives, D. J. G., J. Chem. Soc., 73, 305 (1951).

    Article  Google Scholar 

  2. Hills, G. J., and Ives, D. J. G., Reference Electrodes (edit. by Ives, D. J. G., and Janz, G. J.), 71 (Academic Press, London and New York, 1961).

    Google Scholar 

  3. Hammett, L. P., J. Amer. Chem. Soc., 46, 7 (1924).

    Article  CAS  Google Scholar 

  4. Hammett, L. P., Trans. Farad. Soc., 29, 770 (1933).

    Article  CAS  Google Scholar 

  5. Dolin, P. I., Ershler, B. V., and Frumkin, A. N., Acta Physiochim., 13, 779 (1940).

    CAS  Google Scholar 

  6. Bockris, J. O'M., Modern Aspects of Electrochemistry, 180 (Butterworths Scientific Publications, London, 1954).

    Google Scholar 

  7. Williams, K. R., An Introduction to Fuel Cells, 100 (Elsevier, Amsterdam, 1966).

    Google Scholar 

  8. Justi, E. W., and Winsel, A. W., Kalte Verbrennung Fuel Cells, 63 (Franz Steiner Verlag G. m. b. H., 1962).

  9. Bacon, F. T., Fuel Cells, C. E. P. Technical Manual, 72 (Amer. Inst. Chem. Eng., 1963).

    Google Scholar 

  10. Gillibrand, M. I., Gibson, F., Pearce, L. J., and Watson, R. G. H., Electrochimica Acta, 12, 49 (1967).

    Article  CAS  Google Scholar 

  11. Gillibrand, M. I., and Gray, J., British Patent No. 931732 (1963).

  12. Gillibrand, M. I., Graham, K., and Lomax, G. R., Trans. Farad. Soc., 62, 2895 (1966).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

DUCKWORTH, A., GILLIBBAND, M. & TWENTYMAN, F. Anodic Reactions of the Hydrogen Electrode. Nature 226, 846–847 (1970). https://doi.org/10.1038/226846a0

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1038/226846a0

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing