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Primary Silicon Spherulites in Aluminium–Silicon Alloys

Abstract

WHEN metallic sodium is added to a eutectic aluminium–silicon alloy, the structure of the eutectic silicon is modified by a mechanism which has been described by several authors1–4. Sodium also modifies the structure of primary silicon crystals in this system, and various workers1,5 have stated that a spheroidal form of silicon can be obtained by this means. Evidence that these spherical particles are true Spherulites has not been provided and I wish to describe some preliminary experiments carried out to ascertain the morphology and possible crystallography of these interesting particles.

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References

  1. Davies, V. de L., and West, J. M., J. Inst. Metals, 92, No. 6, 175 (1963–64).

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  2. Bell, J. A. E., and Winegard, W. C., Nature, 208, 177 (1965).

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  3. Day, M. G., and Hellawell, A., J. Inst. Metals, 95, 377 (1968).

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  4. Day, M. G., and Hellawell, A., Proc. Roy. Soc., A, 305, 473 (1968).

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  5. Mascré, C., Proc. Inst. Brit. Foundrymen, 46, 227 (1953).

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DAY, M. Primary Silicon Spherulites in Aluminium–Silicon Alloys. Nature 219, 1357–1358 (1968). https://doi.org/10.1038/2191357a0

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