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Transition in Cellulose in the Vicinity of −30° C

Abstract

THERE has been increasing interest in the investigation of thermal transitions in cellulose. It has been established that the glass transition temperature is in the region 200°–250° C, and there is ample experimental evidence to indicate a transition at 20°–25° C. This transition is also seen in glucose and cellobiose1–3. The purpose of this communication is to report a recently discovered transition at around −30° C, observed in measurements of damping and thermal expansion of paper produced from wood cellulose.

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References

  1. Goring, D. A. I., Proc. Symp. Consolidation of the Paper Web, Cambridge, 1965, 555 (BP and BMA, London, 1966).

  2. Wahba, M., J. Text. Inst., 56, T 218 (1965).

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  3. Ramiah, M. V., and Goring, D. A. I., J. Pol. Sci., C, No. 11, 27 (1965).

  4. Kubát, J., and Lindbergson, B., Svensk Papperstidn., 68, 743 (1965).

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KUBÁT, J., PATTYRANIE, C. Transition in Cellulose in the Vicinity of −30° C. Nature 215, 390–391 (1967). https://doi.org/10.1038/215390a0

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