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Chemiluminescent Reactions of SO with O and with O3

Abstract

THE spectrum of the sulphur dioxide afterglow was first investigated in detail by Gaydon1, who reported that it appeared to be continuous over its entire range from 2400 Å into the visible, apart from some weak bands above 3800 Å which are now known to arise from the (0,0,0) and (0,1,0) levels of the 3B1 state of SO2 (refs. 2 and 3). More recently, Herman et al.4 have investigated the afterglow at low pressures and found no evidence of banded structure; they confirmed Gaydon's view that the afterglow was due to the chemiluminescent combination of O and SO, but did not establish whether it required a third body.

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HALSTEAD, C., THRUSH, B. Chemiluminescent Reactions of SO with O and with O3. Nature 204, 992–993 (1964). https://doi.org/10.1038/204992a0

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