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Four-co-ordinate Complexes of Carbon

Abstract

INVESTIGATIONS in these laboratories of the complexes formed by the 1s2 core (Light) elements, beryllium and boron, with the ditertiary arsine, o-phenylenebis(dimethylarsine) (refs. 1 and 2) (I), have now been extended to carbon. Compounds of the type [CH3AsR3] + X− (X = halogen), have been known for a long time and more recently3 derivatives of the type II and III have also been described.

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References

  1. Clark, R. J. H. (unpublished work).

  2. Chatt, J. C., and Mann, F. G., J. Chem. Soc., 610 (1939).

  3. Glauert, R. H., and Mann, F. G., J. Chem. Soc., 682 (1950). Heaney, H., Heinekey, D. M., Mann, F. G., and Millar, I. T., J. Chem. Soc., 3838 (1958).

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COLLINGE, R., NYHOLM, R. & TOBE, M. Four-co-ordinate Complexes of Carbon. Nature 201, 1322–1323 (1964). https://doi.org/10.1038/2011322a0

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