Abstract
IT is of interest to obtain data on the lattice energy, ΔH00[at.], of solids, and dissociation energies, D00, of gaseous molecules of whole groups of compounds, such as homonuclear molecules1, oxides2, sulphides2, etc., and to study the variation of these properties, or the ratio of these magnitudes, ΔH00[at.]/D00 = α, as a function of the electronic structure of the constituting atoms. An interesting case is that of the sulphides of transition elements.
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References
Verhaegen, G., Stafford, F. E., Goldfinger, P., and Ackerman, M., Eighteenth Intern. Cong. Pure and App. Chem. Montreal, Canada, 1961 (to be published).
Colin, R., and Goldfinger, P. (to be published).
Colin, R., Goldfinger, P., and Jeunehomme, M., Nature, 187, 408 (1960).
Kubaschewski, O., and Evans, E. Ll., Metallurgical Thermochemistry (Pergamou Press, 1953).
Stull, D. R., and Sinke, G. C., Thermodynamic Properties of the Elements, Advances in Chemistry, Ser. 18 (Amer. Chem. Soc., 1956).
Hsiao, C. M., and Schlechten, P. W., J. Metals, 4, 65 (1952).
Ackerman, M., Stafford, F. E., and Drowart, J., J. Chem. Phys., 33, 1784 (1960).
Kapustinskii, A. F., and Korshunov, I. A., (a) Zh. fis. Khim., 13, 278 (1939); (b) Acta Physicochim. U.R.S.S., 10, 259 (1939).
Richardson, F. D., and Jeffes, J. H. E., J. Iron and Steel Inst., 171, 165 (1952).
Anderson, C. T., J. Amer. Chem. Soc., 53, 476 (1931).
Coughlin, J. D., J. Amer. Chem. Soc., 72, 5445 (1950).
White, D., Walsh, P. N., Goldstein, H. W., and Dever, D. P., J. Phys. Chem., 65, 1400, 1404, 1410 (1961); see also Carter, Gilles, and Thorn, J. Chem. Phys., 35, 608 (1961) and Carter, Rauh, and Thorn, J. Chem. Phys., 35, 619 (1961).
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COLIN, R., GOLDFINGER, P. & JEUNEHOMME, M. Existence of Gaseous Sulphides of the Transition Elements : Dissociation Energy of Gaseous MnS. Nature 194, 282–283 (1962). https://doi.org/10.1038/194282a0
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DOI: https://doi.org/10.1038/194282a0
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