Abstract
MOST determinations of stability constants in alkali metal nitrate solvents have concerned the halide complexes of silver1. Recently the cryoscopic2, solubility3, polarographic4, galvanostatic5, spectroscopic6 and e.m.f.7 techniques have been used for investigating the formation of the halide complexes of various metals (for example, cadmium) in these solvents. A silver–silver bromide electrode has been used to study the bromo-complexes of cadmium and lead7. An attempt8 to use the silver–silver chloride electrode in a similar way to study chloro-complexes was not successful.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
For example, Blander, M., J. Phys. Chem., 63, 1262 (1959).
Van Artsdalen, E. R., J. Phys. Chem., 60, 172 (1956).
Duke, F. R., and Iverson, M. L., J. Phys. Chem., 62, 417 (1958).
Christie, J., and Osteryoung, R. A., J. Amer. Chem. Soc., 82, 1841 (1960).
Inman, D., and Bockris, J. O'M., Trans. Farad. Soc., 57, 2308 (1961).
For example, Gruen, D., and McBeth, R. L., J. Phys. Chem., 63, 393 (1959).
Duke, F. R., and Garfinkel, H. M., J. Phys. Chem., 65, 1627 (1961).
Garfinkel, H. M., thesis, see Diss. Abs., 21, 2504 (1961).
Steinberg, M., and Nachtrieb, N. H., J. Amer. Chem. Soc., 72, 3558 (1950).
Leden, I., Z. phys. Chem., A, 188, 160 (1941).
Inman, D., Bockris, J. O'M., and Blomgren, E., J. Electroanal. Chem., 2, 506 (1961).
Flengas, S. N., and Rideal, Sir Eric, Proc. Roy. Soc., A, 233, 443 (1956).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
INMAN, D. Determination of Stability Constants in Molten Alkali Metal Nitrate Solvents. Nature 194, 279–281 (1962). https://doi.org/10.1038/194279a0
Issue Date:
DOI: https://doi.org/10.1038/194279a0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.
