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Oxide Films on Silver at High Temperatures

Abstract

IT is usually assumed that no oxide film can exist on the surface of metallic silver heated in air above 200° C., since bulk silver oxide, when heated in air, decomposes completely into silver and oxygen at this temperature1. Recent work in this laboratory has shown that this is not the case.

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References

  1. Ellingham, H. J. K., J. Soc. Chem. Indust., 63, 125 (1944).

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  2. Hoar, T. P., and Farthing, T. W., Nature, 169, 324 (1952). “Properties of Metallic Surfaces”, Discussion 349 (Institute of Metals, 1953).

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  3. Evans, U. R., “Metallic Corrosion, Passivity and Protection”, 63 (Arnold, London, 1946). Davies, D. E., Evans, U. R., and Agar, J. N., Proc. Roy. Soc., A, 225, 443 (1954).

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  4. Mills, T., and Evans, U. R., J. Chem. Soc., 2182 (1956).

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DAVIES, D. Oxide Films on Silver at High Temperatures. Nature 179, 1293–1294 (1957). https://doi.org/10.1038/1791293b0

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