Abstract
IN a report1 which has just come to our notice, R. A. Rapuano describes results obtained for ultrasonic absorption in carbon disulphide in the frequency range 75–195 Mc./s., which are complementary to initial measurements made by us in the range 30–75 Mc./s. It is shown in the following that the combined results are not only consistent among themselves, but are also compatible with calculations based on the assumption that there is a relaxation of the transfer of energy to the degenerate bending vibration of the carbon disulphide molecule (fundamental frequency2, ν1 = 397 cm.−1 (Table 1)). Measurements to be made in the near future on the temperature-dependence of the ultrasonic absorption over the whole frequency-range covering the dispersion will afford a direct check for this assumption.
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References
Rapuano, R. A., Res. Lab. of Electronics, Massachusetts Institute of Technology, Report No. 151 (April 15, 1950).
Herzberg, G., “Infra-Red and Raman Spectra”, 173 (D. van Nostrand, Inc., 1945).
Lamb, J., and Pinkerton, J. M. M., Proc. Roy. Soc., A, 199, 114 (1949).
Huddart, D. H. A., M.Sc. Thesis, London (1950).
Bazulin, P., J. Exp. Theor. Phys., U.S.S.R., 8, 457 (1938).
Lamb, J., and Huddart, D. H. A., Trans. Farad. Soc., 46, 540 (1950).
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LAMB, J., ANDREAE, J. Ultrasonic Absorption in Carbon Disulphide. Nature 167, 898–899 (1951). https://doi.org/10.1038/167898a0
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DOI: https://doi.org/10.1038/167898a0
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