Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Article
  • Published:

Tautomerism and Elimination

Abstract

About twenty years ago the outlook on theoretical problems connected with tautomerism was considerably enlarged by the proposal to regard tautomeric changes, for certain purposes, as internal analogues of additivereactions1; thus the study of ring-chain tautomerism developed as a direct consequence of this point of view. It is curious that the complementary and equally valid idea of regarding tautomeric change as an internal form of elimination seems never to have been explored. Consideration shows that it leads to many striking analogies and correlations. This note is confined to a single illustration chosen because it happens to be simply explicable in terms of the preceding communication,

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Ingold, E. H., Chem. and Ind., 42, 1246 (1923); J. Chem. Soc., 123, 1717 (1923).

    Article  Google Scholar 

  2. J. Chem. Soc., 1434 (1938).

  3. Cf. Kon and May, J. Chem. Soc., 1549 (1927); Ingold, Ann. Rep. Chem. Soc., 24, 112 (1927).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

HUGHES, E. Tautomerism and Elimination. Nature 147, 813–814 (1941). https://doi.org/10.1038/147813a0

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/147813a0

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing